Photovoltaic Switching Mechanism in Lateral Structure Hybrid Perovskite Solar Cells

被引:608
作者
Yuan, Yongbo [1 ]
Chae, Jungseok [2 ,3 ]
Shao, Yuchuan [1 ]
Wang, Qi [1 ]
Xiao, Zhengguo [1 ]
Centrone, Andrea [2 ]
Huang, Jinsong [1 ]
机构
[1] Univ Nebraska, Dept Mech & Mat Engn, Lincoln, NE 68588 USA
[2] NIST, Ctr Nanoscale Sci & Technol, Gaithersburg, MD 20899 USA
[3] Univ Maryland, Maryland Nanoctr, College Pk, MD 20742 USA
基金
美国国家科学基金会;
关键词
electrical doping; ionic electromigrations; perovskite solar cells; photothermal induced resonance; switchable photovoltaic; INFRARED-SPECTROSCOPY; HIGH-PERFORMANCE; HYSTERESIS; PHOTODETECTORS; NANOSCALE; RESOLUTION; EMERGENCE; LIGHT;
D O I
10.1002/aenm.201500615
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Long range electromigration of methylammonium ions (MA+) in methyl ammonium lead tri-iodide (MAPbI3) film is observed directly using the photothermal induced resonance technique. The electromigration of MA+ leads to the formation of a lateral p-i-n structure, which is the origin of the switchable photovoltaic effect in MAPbI3 perovskite devices. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
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页数:7
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