Synthesis based on the wet impregnation method and characterization of iron and iron oxide-silica nanocomposites

被引:35
作者
Alcala, M. D. [1 ]
Real, C. [1 ]
机构
[1] CSIC, US, Inst Ciencia Mat Sevilla, Ctr Mixto, Seville 41092, Spain
关键词
iron; magnetite; maghemite; hematite; silica matrix; nanocomposites; magnetic properties;
D O I
10.1016/j.ssi.2006.01.019
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The present work describes an easy procedure for the preparation of iron-silica and iron oxide-silica composites using the wet impregnation method and subsequent heat treatment in different atmospheres. In this way, a specific composite can be produced with a high content of iron or an iron oxide phase (about 24wt.%) uniformly dispersed in the silica matrix. No pre-treatment before calcinations was necessary to obtain the magnetic phases. Material characterization is also reported. (c) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码:955 / 960
页数:6
相关论文
共 38 条
[1]   Synthesis of iron oxide nanoparticles used as MRI contrast agents: A parametric study [J].
Babes, L ;
Denizot, B ;
Tanguy, G ;
Le Jeune, JJ ;
Jallet, P .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1999, 212 (02) :474-482
[2]   Syntheses of Fe2O3/silica red inorganic inclusion pigments for ceramic applications [J].
Bondioli, F ;
Ferrari, AM ;
Leonelli, C ;
Manfredini, T .
MATERIALS RESEARCH BULLETIN, 1998, 33 (05) :723-729
[3]  
Bourlinos A, 2001, ADV MATER, V13, P289, DOI 10.1002/1521-4095(200102)13:4<289::AID-ADMA289>3.0.CO
[4]  
2-U
[5]   Magnetic properties of γ-Fe2O3-SiO2 aerogel and xerogel nanocomposite materials [J].
Cannas, C ;
Casula, MF ;
Concas, G ;
Corrias, A ;
Gatteschi, D ;
Falqui, A ;
Musinu, A ;
Sangregorio, C ;
Spano, G .
JOURNAL OF MATERIALS CHEMISTRY, 2001, 11 (12) :3180-3187
[6]   Epitaxy of Fe/Cu/Si(111) ultrathin films: an Auger electron diffraction study [J].
Castrucci, P ;
Gunnella, R ;
Bernardini, R ;
Montecchiari, A ;
Carboni, R ;
De Crescenzi, M .
SURFACE SCIENCE, 2001, 482 :916-921
[7]  
CASULA MF, 2001, J NONCRYST SOLIDS, V25, P293
[8]   Factors influencing the texture and stability of maghemite obtained from the thermal decomposition of lepidocrocite [J].
Chopra, GS ;
Real, C ;
Alcalá, MD ;
Pérez-Maqueda, LA ;
Subrt, J ;
Criado, JM .
CHEMISTRY OF MATERIALS, 1999, 11 (04) :1128-1137
[9]   Magnetic hysteresis in Fe/SiO2 and Fe/BN granular solids [J].
Christodoulides, JA ;
Hadjipanayis, GC .
SYNTHESIS AND PROPERTIES OF MECHANICALLY ALLOYED AND NANOCRYSTALLINE MATERIALS, PTS 1 AND 2 - ISMANAM-96, 1997, 235-2 :651-657
[10]  
Cornell R. M., 1996, The Iron Oxides