Coordination Chemistry of Neutral (Ln)-Z Amphoteric and Ambiphilic Ligands

被引:154
作者
Fontaine, Frederic-Georges [1 ]
Boudreau, Josee [1 ]
Thibault, Marie-Helene [1 ]
机构
[1] Univ Laval, Dept Chim, Quebec City, PQ G1V 0A6, Canada
基金
加拿大自然科学与工程研究理事会;
关键词
Ambiphilic ligands; Amphoteric ligands; Bifunctional ligands; Lewis acids;
D O I
10.1002/ejic.200800784
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
This review focuses on the coordination chemistry of neutral ambiphilic and amphoteric ligands, The various designs of molecules having both donor and acceptor moieties and the strategies to prevent self-aggregation and favour transition-metal coordination will be discussed. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008)
引用
收藏
页码:5439 / 5454
页数:16
相关论文
共 134 条
[1]   Dibenzophosphaborin:: A hetero-π-conjugated molecule with fluorescent properties based on intramolecular charge transfer between phosphorus and boron atoms [J].
Agou, T ;
Kobayashi, J ;
Kawashima, T .
ORGANIC LETTERS, 2005, 7 (20) :4373-4376
[2]   Transition metal boryl and borylene complexes: substitution and abstraction chemistry [J].
Aldridge, S ;
Coombs, DL .
COORDINATION CHEMISTRY REVIEWS, 2004, 248 (7-8) :535-559
[3]  
[Anonymous], 2002, BIOINORGANIC CHEM SH, DOI DOI 10.1002/0471265330
[4]   CONTRIBUTIONS TO THE CHEMISTRY OF BORON .230. ELECTROPHILIC BORYLATION OF METALLOCENES - SYNTHESIS AND MOLECULAR-STRUCTURES OF 1,1',3,3'-TETRAKIS(DIBROMOBORYL)METALLOCENES OF THE IRON TRIAD [J].
APPEL, A ;
NOTH, H ;
SCHMIDT, M .
CHEMISCHE BERICHTE, 1995, 128 (06) :621-626
[5]   Fe-B bonding in (dibromoboryl)ferrocene: A structural and theoretical investigation [J].
Appel, A ;
Jakle, F ;
Priermeier, T ;
Schmid, R ;
Wagner, M .
ORGANOMETALLICS, 1996, 15 (04) :1188-1194
[6]   Reactions of titanium and zirconium derivatives of bis(trimethylsilyl)acetylene with tris(pentafluorophenyl)borane: A titanium(III) complex of an alkynylboranate [J].
Arndt, P ;
Baumann, W ;
Spannenberg, A ;
Rosenthal, U ;
Burlakov, VV ;
Shur, VB .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (12) :1414-1418
[7]   REACTIONS OF ORGANORUTHENIUM PHOSPHINE COMPLEXES WITH HYDROBORATING REAGENTS [J].
BAKER, RT ;
CALABRESE, JC ;
WESTCOTT, SA ;
MARDER, TB .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (34) :8777-8784
[8]   Main group compounds as amphoteric ligands to transition metals. Synthesis and molecular structure of Cr(CO)(5)[PPh(2)CH(2)Ga(CH(2)CMe(3))(2)center dot NM(3)] [J].
Beachley, OT ;
Banks, MA ;
Kopasz, JP ;
Rogers, RD .
ORGANOMETALLICS, 1996, 15 (24) :5170-5174
[9]   Chemical bonding in phosphane and amine complexes of main group elements and transition metals [J].
Bessac, Fabienne ;
Frenking, Gernot .
INORGANIC CHEMISTRY, 2006, 45 (17) :6956-6964
[10]   Redox activation of a B-H bond: a new route to metallaboratrane complexes [J].
Blagg, Robin J. ;
Charmant, Jonathan P. H. ;
Connelly, Neil G. ;
Haddow, Mairi F. ;
Orpen, A. Guy .
CHEMICAL COMMUNICATIONS, 2006, (22) :2350-2352