Synthesis, characterization and thermal properties of polymer/magnetite nanocomposites

被引：88

作者：

Dallas, Panagiotis ^{[1
]}

Georgakilas, Vasilios

Niarchos, Dimitrios

Komninou, Philomela

Kehagias, Thomas

Petridis, Dimitrios

机构：

[1] NCSR Demokritos, Inst Mat Sci, Athens 15310, Greece

[2] Aristotle Univ Thessaloniki, Dept Phys, Thessaloniki, Greece

来源：

NANOTECHNOLOGY | 2006年 / 17卷 / 08期

关键词：

D O I：

10.1088/0957-4484/17/8/043

中图分类号：

TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

A new procedure for the preparation of polymer/magnetic nanoparticle composites is described. Magnetite nanoparticles capped with methacrylate units were dispersed in a toluene solution of the monomer, and polymerization occurred after the addition of the initiator a'-a-azo-iso-butyronitrile at reflux temperature. The structural properties were determined by infrared spectroscopy, x-ray diffractometry and transmission electron microscopy. The thermal properties of the resulting nanocomposite were studied extensively with modulated differential scanning calorimetry. An increase in the glass transition temperature was observed after the incorporation of the nanoparticles.

引用

页码：2046 / 2053

页数：8

共 44 条

[1] PREPARATION AND CHARACTERIZATION OF FE2O3 NANOPARTICLES IN MESOPOROUS SILICATE [J].

ABE, T ;

TACHIBANA, Y ;

UEMATSU, T ;

IWAMOTO, M .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1995, (16) :1617-1618

[2] Semiconductor clusters, nanocrystals, and quantum dots [J].

Alivisatos, AP .

SCIENCE, 1996, 271 (5251) :933-937

[3] Synthesis and characterization of magnetically modified clay composites [J].

Bourlinos, AB ;

Karakassides, MA ;

Simopoulos, A ;

Petridis, D .

CHEMISTRY OF MATERIALS, 2000, 12 (09) :2640-2645

[4]

Bourlinos AB, 2002, CHEM MATER, V14, P899, DOI [10.1021/cm010794w, 10.1021/cm01O794w]

[5] Magnetic modification of the external surfaces in the MCM-41 porous silica: Synthesis, characterization, and functionalization [J].

Bourlinos, AB ;

Simopoulos, A ;

Boukos, N ;

Petridis, D .

JOURNAL OF PHYSICAL CHEMISTRY B, 2001, 105 (31) :7432-7437

[6]

BOURLINOS AB, 2005, IN PRESS J MAT SCI

[7] Synthesis and characterization of polypyrrole-magnetite-silica particles [J].

Butterworth, MD ;

Bell, SA ;

Armes, SP ;

Simpson, AW .

JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1996, 183 (01) :91-99

[8] Synthesis, characterization, and magnetic properties of Fe3O4 thin films prepared via a sol-gel method [J].

Chang, HSW ;

Chiou, CC ;

Chen, YW ;

Sheen, SR .

JOURNAL OF SOLID STATE CHEMISTRY, 1997, 128 (01) :87-92

[9] Modification and characterization of polystyrene-based magnetic microspheres and comparison with albumin-based magnetic microspheres [J].

Chatterjee, J ;

Haik, Y ;

Chen, CJ .

JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, 2001, 225 (1-2) :21-29

[10]

Fendler J. H., 1998, NANOPARTICLES NANOST

← 1 2 3 4 5 →