Thiacrown ether as regulator of lipase-catalyzed trans-esterification in organic media: Practical optical resolution of allyl alcohols

被引：40

作者：

Takagi, Y

Teramoto, J

Kihara, H

Itoh, T

Tsukube, H

机构：

[1] OKAYAMA UNIV,FAC EDUC,DEPT CHEM,OKAYAMA 700,JAPAN

[2] OSAKA CITY UNIV,FAC SCI,DEPT CHEM,OSAKA 558,JAPAN

来源：

TETRAHEDRON LETTERS | 1996年 / 37卷 / 28期

关键词：

D O I：

10.1016/0040-4039(96)00991-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Thiacrown ether additive enhanced enantioselectivity in lipase-catalyzed trans-esterification of allyl alcohols. Small amounts of thiacrown ether offered highly enantioselective reaction when 5-phenylpentene-3-ol was subjected to the reaction of Pseudomonas cepacia lipase. Copyright (C) 1996 Elsevier Science Ltd

引用

页码：4991 / 4992

页数：2

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