An Amorphous Red Phosphorus/Carbon Composite as a Promising Anode Material for Sodium Ion Batteries

被引：812

作者：

Kim, Youngjin ^{[1
]}

Park, Yuwon ^{[1
,2
,3
]}

Choi, Aram ^{[2
,3
]}

Choi, Nam-Soon ^{[2
,3
]}

Kim, Jeongsoo ^{[4
]}

Lee, Junesoo ^{[4
]}

Ryu, Ji Heon ^{[5
]}

Oh, Seung M. ^{[1
]}

Lee, Kyu Tae ^{[2
,3
]}

机构：

[1] Seoul Natl Univ, Sch Chem & Biol Engn, Seoul 151742, South Korea

[2] Ulsan Natl Inst Sci & Technol, Interdisciplinary Sch Green Energy, Ulsan 689798, South Korea

[3] Ulsan Natl Inst Sci & Technol, KIER UNIST Adv Ctr Energy, Ulsan 689798, South Korea

[4] SK Innovat Co, Taejon 305712, South Korea

[5] Korea Polytech Univ, Grad Sch Knowledge Based Technol & Energy, Gyeonggi 429793, South Korea

来源：

ADVANCED MATERIALS | 2013年 / 25卷 / 22期

基金：

新加坡国家研究基金会;

关键词：

electrochemistry; sodium ion batteries; anode material; phosphorus; composite; HIGH-CAPACITY; LI-ION; NEGATIVE ELECTRODES; BLACK PHOSPHORUS; CARBON; STORAGE; PERFORMANCE; CHALLENGES; TEREPHTHALATE; POLYACRYLATE;

D O I：

10.1002/adma.201204877

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An amorphous red phosphorus/carbon composite is obtained through a facile and simple ball milling process, and its electrochemical performance as an anode material for Na ion batteries is evaluated. The composite shows excellent electrochemical performance including a high specific capacity of 1890 mA h g-1, negligible capacity fading over 30 cycles, an ideal redox potential (0.4 V vs. Na/Na+), and an excellent rate performance, thus making it a promising candidate for Na ion batteries. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：3045 / 3049

页数：5

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