Covalent hybrid materials based on nanolatex particles and Dawson polyoxometalates

被引：41

作者：

Cannizzo, C

Mayer, CR

Sécheresse, F

Larpent, C

机构：

[1] Univ Versailles, CNRS, IREM, UMR 8637, F-78035 Versailles, France

[2] Univ Versailles, CNRS, SIRCOB, UMR 8086, F-78035 Versailles, France

来源：

ADVANCED MATERIALS | 2005年 / 17卷 / 23期

关键词：

D O I：

10.1002/adma.200500685

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new nanohybrid organic-inorganic material is synthesized from a nanolatex U particle organic core and a functionalized Dawson polyoxotungstate inorganic shell (see Figure). The host matrix is covalently attached to the inorganic moieties through a thiol function.

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页码：2888 / +

页数：6

相关论文

共 36 条

[1] Ultrafine selective metal-complexing nanoparticles: Synthesis by microemulsion copolymerization, binding capacity, and ligand accessibility [J].

Amigoni-Gerbier, S ;

Desert, S ;

Gulik-Kryswicki, T ;

Larpent, C .

MACROMOLECULES, 2002, 35 (05) :1644-1650

[2]

ANIZZO C, 2005, POLYMER, V46, P1269

[3] MIXED-VALENCE POLYOXOMETALATE CLUSTERS .2. DELOCALIZATION OF ELECTRONIC PAIRS IN 18-SITE HETEROPOLY BLUES WITH WELLS-DAWSON STRUCTURE [J].

BORRASALMENAR, JJ ;

CLEMENTE JUAN, JM ;

CORONADO, E ;

TSUKERBLAT, BS .

CHEMICAL PHYSICS, 1995, 195 (1-3) :17-28

[4] Multilayered titania, silica, and Laponite nanoparticle coatings on polystyrene colloidal templates and resulting inorganic hollow spheres [J].

Caruso, RA ;

Susha, A ;

Caruso, F .

CHEMISTRY OF MATERIALS, 2001, 13 (02) :400-409

[5] Nanostructured hybrid materials from aqueous polymer dispersions [J].

Castelvetro, Valter ;

De Vita, Cinzia .

Advances in Colloid and Interface Science, 2004, 108-109 :167-185

[6] Nanocomposite multilayer film of a ruthenium metallodendrimer and a Dawson-type polyoxometalate as a bifunctional electrocatalyst [J].

Cheng, L ;

Cox, JA .

CHEMISTRY OF MATERIALS, 2002, 14 (01) :6-+

[7] Gold nanoparticles: Assembly, supramolecular chemistry, quantum-size-related properties, and applications toward biology, catalysis, and nanotechnology [J].

Daniel, MC ;

Astruc, D .

CHEMICAL REVIEWS, 2004, 104 (01) :293-346

[8]

Farmer SC, 2001, CHEM MATER, V13, P3920, DOI [10.1021/cm010291q, 10.1021/cm01029lq]

[9] Main-group element, organic, and organometallic derivatives of polyoxometalates [J].

Gouzerh, P ;

Proust, A .

CHEMICAL REVIEWS, 1998, 98 (01) :77-111

[10] Polymerization of and within self-organized media [J].

Hentze, HP ;

Kaler, EW .

CURRENT OPINION IN COLLOID & INTERFACE SCIENCE, 2003, 8 (02) :164-178

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