Organophosphorus flame-retardant and plasticizer analysis, including recommendations from the first worldwide interlaboratory study

被引：109

作者：

Brandsma, Sicco H. ^{[1
]}

de Boer, Jacob ^{[1
]}

Cofino, Wim P. ^{[2
]}

Covaci, Adrian ^{[3
]}

Leonards, Pim E. G. ^{[1
]}

机构：

[1] Vrije Univ Amsterdam, Inst Environm Studies, NL-1081 HV Amsterdam, Netherlands

[2] Univ Wageningen & Res Ctr, NL-6700 EW Wageningen, Netherlands

[3] Univ Antwerp, Toxicol Ctr, B-2610 Antwerp, Belgium

来源：

TRAC-TRENDS IN ANALYTICAL CHEMISTRY | 2013年 / 43卷

关键词：

Analytical performance; Blank contamination; Dust; Fish oil; Flame retardant; Interlaboratory study; Organophosphorus flame retardant (PFR); Plasticizer; Sediment; Standard solution; TANDEM MASS-SPECTROMETRY; INDOOR ENVIRONMENTS; GAS-CHROMATOGRAPHY; POPULATION CHARACTERISTICS; CHEMICAL-IONIZATION; ORGANIC-COMPOUNDS; PHTHALATE-ESTERS; WATER SAMPLES; NEW-MODEL; AIR;

D O I：

10.1016/j.trac.2012.12.004

中图分类号：

O65 [分析化学];

学科分类号：

070302 [分析化学];

摘要：

The first worldwide interlaboratory study on organophosphorus flame retardants (PFRs) was organized to improve the quality of the data reported in the literature. The study involved standard solutions, dust, fish oil and sediment samples. The differences in coefficients of variation (CV) between the samples were related more to PFR concentration (with high blanks being reported by some laboratories) and less to matrix type. Not all participating laboratories suffered from blank problems, which indicated that it was possible to control the blanks. We include recommendations on how to improve analytical performance, especially to reduce contamination of blanks. (C) 2012 Elsevier Ltd. All rights reserved.

引用

页码：217 / 228

页数：12

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