Functional group effects on metal-organic framework topology

被引：47

作者：

Dau, Phuong V. ^{[1
]}

Tanabe, Kristine K. ^{[1
]}

Cohen, Seth M. ^{[1
]}

机构：

[1] Univ Calif San Diego, Dept Chem & Biochem, La Jolla, CA 92093 USA

来源：

CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 75期

基金：

美国国家科学基金会;

关键词：

COORDINATION POLYMERS; CRYSTAL-STRUCTURES; HYDROGEN STORAGE; BUILDING UNITS; CARBON-DIOXIDE; SURFACE-AREA; TPT=2,4,6-TRI(4-PYRIDYL)-1,3,5-TRIAZINE; MOLECULES; POROSITY; SORPTION;

D O I：

10.1039/c2cc34938h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Functionalization of the ligand 1,3,5-tris(4-carboxyphenyl)benzene (H3BTB) has been realized with methoxy (H3BTB-[OMe](3)) and hydroxy (H3BTB-[OH](3)) groups. Combining H3BTB-[OMe](3) and Zn(II) results in the formation of the first isostructural, functionalized analogue of MOF-177 (MOF-177-OMe), while the combination of H3BTB-[OH](3) and Zn(II) generates a rare, interpenetrated pcu-e framework.

引用

页码：9370 / 9372

页数：3

共 30 条

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