Large-Pore Apertures in a Series of Metal-Organic Frameworks

被引：1753

作者：

Deng, Hexiang ^{[1
,2
]}

Grunder, Sergio ^{[3
]}

Cordova, Kyle E. ^{[1
,2
]}

Valente, Cory ^{[3
]}

Furukawa, Hiroyasu ^{[1
,2
]}

Hmadeh, Mohamad ^{[1
,2
]}

Gandara, Felipe ^{[1
,2
]}

Whalley, Adam C. ^{[3
]}

Liu, Zheng ^{[4
]}

Asahina, Shunsuke ^{[5
]}

Kazumori, Hiroyoshi ^{[5
]}

O'Keeffe, Michael ^{[1
,2
]}

Terasaki, Osamu ^{[6
,7
,8
,9
]}

Stoddart, J. Fraser ^{[3
,8
,9
]}

Yaghi, Omar M. ^{[1
,2
,8
,9
]}

机构：

[1] Univ Calif Los Angeles, Ctr Global Mentoring, Ctr Reticular Chem, US Dept Energy DOE,Inst Genom & Prote, Los Angeles, CA 90095 USA

[2] Univ Calif Los Angeles, Dept Chem & Biochem, Los Angeles, CA 90095 USA

[3] Northwestern Univ, Dept Chem, Ctr Chem Integrated Syst, Evanston, IL 60208 USA

[4] Natl Inst Adv Ind Sci & Technol, Nanotube Res Ctr, Tsukuba, Ibaraki 3050046, Japan

[5] JEOL, SMBU, Tokyo 1968558, Japan

[6] Stockholm Univ, Dept Mat & Environm Chem, S-10691 Stockholm, Sweden

[7] Stockholm Univ, EXSELENT, S-10691 Stockholm, Sweden

[8] World Class Univ, NanoCentury KAIST Inst, Taejon 305701, South Korea

[9] World Class Univ, Grad Sch Energy Environm Water & Sustainabil, Taejon 305701, South Korea

来源：

SCIENCE | 2012年 / 336卷 / 6084期

基金：

瑞士国家科学基金会;

关键词：

CRYSTAL-STRUCTURE; BUILDING UNITS; CATALYSIS; STORAGE; DESIGN; POROSITY; PLATFORM; LIGAND; SITES; CAGES;

D O I：

10.1126/science.1220131

中图分类号：

O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];

学科分类号：

07 ; 0710 ; 09 ;

摘要：

We report a strategy to expand the pore aperture of metal-organic frameworks (MOFs) into a previously unattained size regime (>32 angstroms). Specifically, the systematic expansion of a well-known MOF structure, MOF-74, from its original link of one phenylene ring (I) to two, three, four, five, six, seven, nine, and eleven (II to XI, respectively), afforded an isoreticular series of MOF-74 structures (termed IRMOF-74-I to XI) with pore apertures ranging from 14 to 98 angstroms. All members of this series have non-interpenetrating structures and exhibit robust architectures, as evidenced by their permanent porosity and high thermal stability (up to 300 degrees C). The pore apertures of an oligoethylene glycol-functionalized IRMOF-74-VII and IRMOF-74-IX are large enough for natural proteins to enter the pores.

引用

页码：1018 / 1023

页数：6

共 33 条

[1] TEMPLATING OF MESOPOROUS MOLECULAR-SIEVES BY NONIONIC POLYETHYLENE OXIDE SURFACTANTS [J].

BAGSHAW, SA ;

PROUZET, E ;

PINNAVAIA, TJ .

SCIENCE, 1995, 269 (5228) :1242-1244

[2] Design, chirality, and flexibility in nanoporous molecule-based materials [J].

Bradshaw, D ;

Claridge, JB ;

Cussen, EJ ;

Prior, TJ ;

Rosseinsky, MJ .

ACCOUNTS OF CHEMICAL RESEARCH, 2005, 38 (04) :273-282

[3] Mechanical gas capture and release in a network solid via multiple single-crystalline transformations [J].

Chandler, Brett D. ;

Enright, Gary D. ;

Udachin, Konstantin A. ;

Pawsey, Shane ;

Ripmeester, John A. ;

Cramb, David T. ;

Shimizu, George K. H. .

NATURE MATERIALS, 2008, 7 (03) :229-235

[4] Base-induced formation of two magnesium metal-organic framework compounds with a bifunctional tetratopic ligand [J].

Dietzel, Pascal D. C. ;

Blom, Richard ;

Fjellvag, Helmer .

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2008, (23) :3624-3632

[5] Hydrogen storage in a microporous metal-organic framework with exposed Mn2+ coordination sites [J].

Dinca, Mircea ;

Dailly, Anne ;

Liu, Yun ;

Brown, Craig M. ;

Neumann, Dan. A. ;

Long, Jeffrey R. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (51) :16876-16883

[6] Systematic design of pore size and functionality in isoreticular MOFs and their application in methane storage [J].

Eddaoudi, M ;

Kim, J ;

Rosi, N ;

Vodak, D ;

Wachter, J ;

O'Keeffe, M ;

Yaghi, OM .

SCIENCE, 2002, 295 (5554) :469-472

[7] Designed synthesis of 3D covalent organic frameworks [J].

El-Kaderi, Hani M. ;

Hunt, Joseph R. ;

Mendoza-Cortes, Jose L. ;

Cote, Adrien P. ;

Taylor, Robert E. ;

O'Keeffe, Michael ;

Yaghi, Omar M. .

SCIENCE, 2007, 316 (5822) :268-272

[8]

Farha OK, 2010, NAT CHEM, V2, P944, DOI [10.1038/NCHEM.834, 10.1038/nchem.834]

[9] Crystal structure, dissolution, and deposition of a 5 nm functionalized metal-organic great rhombicuboctahedron [J].

Furukawa, Hiroyasu ;

Kim, Jaheon ;

Plass, Katherine E. ;

Yaghi, Omar M. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (26) :8398-8399

[10] Isoreticular Expansion of Metal-Organic Frameworks with Triangular and Square Building Units and the Lowest Calculated Density for Porous Crystals [J].

Furukawa, Hiroyasu ;

Go, Yong Bok ;

Ko, Nakeun ;

Park, Young Kwan ;

Uribe-Romo, Fernando J. ;

Kim, Jaheon ;

O'Keeffe, Michael ;

Yaghi, Omar M. .

INORGANIC CHEMISTRY, 2011, 50 (18) :9147-9152

← 1 2 3 4 →