[(CyPF-tBu)PdCl2]:: An air-stable, one-component, highly efficient catalyst for amination of heteroaryl and aryl halides

被引：124

作者：

Shen, Qilong

Hartwig, John F. ^{[1
]}

机构：

[1] Univ Illinois, Dept Chem, Urbana, IL 61801 USA

来源：

ORGANIC LETTERS | 2008年 / 10卷 / 18期

关键词：

D O I：

10.1021/ol801615u

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An air- and moisture-stable palladium catalyst, [(CyPF-Bu-t)PdCl2] (1), for coupling of heteroaryl chlorides, bromides, and iodides with a variety of primary amines is described. Most of these reactions occurred in high yield with 0.001-0.05 mol % catalyst loading. The reactions tolerated a wide range of functional groups.

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页码：4109 / 4112

页数：4

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