Design of improved deep eutectic solvents using hole theory

被引:406
作者
Abbott, AR [1 ]
Capper, G [1 ]
Gray, S [1 ]
机构
[1] Univ Leicester, Dept Chem, Leicester LE1 7RH, Leics, England
关键词
fluorinated ligands; hydrogen bonds; ionic liquids; surface tension; viscosity;
D O I
10.1002/cphc.200500489
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
(Figure presented) Extraordinary solvents: The authors design deep eutectic solvents (DESs) based on small cations and fluorinated hydrogen-bond donors (see figure). These DESs display properties of decreased viscosity and increased conductivity with differences up to four orders of magnitude compared to ionic liquids. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码:803 / 806
页数:4
相关论文
共 15 条
[1]   Model for the conductivity of ionic liquids based on an infinite dilution of holes [J].
Abbott, AP .
CHEMPHYSCHEM, 2005, 6 (12) :2502-2505
[2]   Selective extraction of metals from mixed oxide matrixes using choline-based ionic liquids [J].
Abbott, AP ;
Capper, G ;
Davies, DL ;
Rasheed, RK ;
Shikotra, P .
INORGANIC CHEMISTRY, 2005, 44 (19) :6497-6499
[3]   Electropolishing of stainless steel in an ionic liquid [J].
Abbott, AP ;
Capper, G ;
Swain, BG ;
Wheeler, DA .
TRANSACTIONS OF THE INSTITUTE OF METAL FINISHING, 2005, 83 (01) :51-53
[4]   Application of hole theory to the viscosity of ionic and molecular liquids [J].
Abbott, AP .
CHEMPHYSCHEM, 2004, 5 (08) :1242-1246
[5]   Deep eutectic solvents formed between choline chloride and carboxylic acids: Versatile alternatives to ionic liquids [J].
Abbott, AP ;
Boothby, D ;
Capper, G ;
Davies, DL ;
Rasheed, RK .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (29) :9142-9147
[6]   Novel solvent properties of choline chloride/urea mixtures [J].
Abbott, AP ;
Capper, G ;
Davies, DL ;
Rasheed, RK ;
Tambyrajah, V .
CHEMICAL COMMUNICATIONS, 2003, (01) :70-71
[7]  
BOCKRIS JOM, 1970, MODERN ELECTROCHEMIS, V1, pCH6
[8]  
Wasserscheid P, 2000, ANGEW CHEM INT EDIT, V39, P3772, DOI 10.1002/1521-3773(20001103)39:21<3772::AID-ANIE3772>3.0.CO
[9]  
2-5
[10]  
Wasserscheid P., 2003, Ionic Liquids in synthesis