Asymmetric hydrogenation of cyclic imines with an ionic Cp*Rh(III) catalyst

被引：184

作者：

Li, Chaoqun ^{[1
]}

Xiao, Jianliang ^{[1
]}

机构：

[1] Univ Liverpool, Liverpool Ctr Mat & Catalysis, Dept Chem, Liverpool L69 7ZD, Merseyside, England

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2008年 / 130卷 / 40期

基金：

英国工程与自然科学研究理事会;

关键词：

D O I：

10.1021/ja8050958

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

When associated with a noncoordinating bulky conunteranion, a cationic Cp*Rh(III)-diamine catalyst displayed excellent enantioselectivities in asymmetric hydrogenation of cyclic imines, affording bioactive tetrahydroisoquinolines and tetrahydro-beta-carbolines frequently with 99% ee's.

引用

收藏

页码：13208 / 13209

页数：2

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