Uranium complexes of multidentate N-donor ligands

被引：248

作者：

Sessler, Jonathan L. ^{[1
]}

Melfi, Patricia J. ^{[1
]}

Pantos, G. Dan ^{[1
]}

机构：

[1] Univ Texas, Dept Chem & Biochem, Austin, TX 78712 USA

来源：

COORDINATION CHEMISTRY REVIEWS | 2006年 / 250卷 / 7-8期

关键词：

uranium; actinides; nitrogen; pyrrole; pyridine; salen; salophen; amido; scorpionate; carbazone; coordination complexes;

D O I：

10.1016/j.ccr.2005.10.007

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

This review focuses on uranium cation coordination complexes with multidentate nitrogen-containing ligands appearing in the literature from 2000 to mid-2005, with reports prior to 2000 included where pertinent. In addition to the uranyl cation (UO22+), special attention will be paid to tri and tetravalent uranium species, for which recent reports have provided new insights into actinide chemistry. The ligands discussed can be separated into five main categories: pyrrole, pyridine, amido, Schiff-base salicylidene-derived and other miscellaneous type ligands. Manipulation of the steric bulk and rigidity of these ligands is essential for exploring the reactivity and bonding behavior of uranium cations. Additionally, applications of such complexes, including small molecule activation, catalysis, actinide sensors and incorporation into liquid crystals will be discussed. (c) 2005 Elsevier B.V. All rights reserved.

引用

页码：816 / 843

页数：28

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