Soluble Conjugated Microporous Polymers

被引：196

作者：

Cheng, Ge ^{[1
,2
]}

Hasell, Tom ^{[1
,2
]}

Trewin, Abbie ^{[1
,2
]}

Adams, Dave J. ^{[1
,2
]}

Cooper, Andrew I. ^{[1
,2
]}

机构：

[1] Univ Liverpool, Dept Chem, Liverpool L69 3BX, Merseyside, England

[2] Univ Liverpool, Ctr Mat Discovery, Liverpool L69 3BX, Merseyside, England

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2012年 / 51卷 / 51期

基金：

英国工程与自然科学研究理事会;

关键词：

absorption; dendrimers; membranes; polymers; selectivity; INTRINSIC MICROPOROSITY; SURFACE-AREA; NETWORKS; FRAMEWORKS; OCTAVINYLSILSESQUIOXANE;

D O I：

10.1002/anie.201205521

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Soluble and porous: Soluble conjugated microporous polymers (SCMPs) can be prepared by synthesizing discrete hyperbranched molecules. The materials can be cast from solution as thin films (see picture), suggesting a range of processing options that are not available for insoluble CMP networks. Soluble, conjugated dendrimers are porous and give insight into the structural origin of microporosity. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：12727 / 12731

页数：5

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