Temperature-sensitive core-shell microgel particles with dense shell

被引：147

作者：

Berndt, I

Pedersen, JS

Richtering, W

机构：

[1] Rhein Westfal TH Aachen, Inst Chem Phys, Lehrtuhl Phys Chem 2, D-52056 Aachen, Germany

[2] Aarhus Univ, Dept Chem, DK-8000 Aarhus C, Denmark

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 11期

关键词：

block copolymers; core-shell nanoparticles; microgels; neutron scattering; temperature sensitivity;

D O I：

10.1002/anie.200503888

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Graph Presented) Cores and effect: Using different temperature-sensitive polymers a core-shell microgel is prepared, which at intermediate temperatures has a shell with a higher segment density Φ than the core (see radial density profiles: core (red), shell (blue)). More detailed information is obtained from small-angle neutron scattering. A new form-factor model describes the experimental scattering curves at different temperatures. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

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页码：1737 / 1741

页数：5

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