Cyclic single-molecule magnet in heterospin system

被引：81

作者：

Yoshihara, Daisuke ^{[1
]}

Karasawa, Satoru ^{[1
]}

Koga, Noboru ^{[1
]}

机构：

[1] Kyushu Univ, Grad Sch Pharmaceut Sci, Higashi Ku, Fukuoka 8128582, Japan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2008年 / 130卷 / 32期

关键词：

D O I：

10.1021/ja802895d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The 2:2 complex of Co-carbene is generated by photolysis of [Co(hfpip)(2) (D2py(2)(TBA))](2), 1, having a cyclic structure functioning as a single-molecule magnet with U-eff = 96 K and H-c = 10 kOe at 1.9 K after annealing at 70 K.

引用

页码：10460 / +

页数：3

共 13 条

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