Development of a mobile system based on laser-induced breakdown spectroscopy and dedicated to in situ analysis of polluted soils

被引:57
作者
Bousquet, B. [1 ]
Travaille, G. [1 ]
Ismael, A. [1 ]
Canioni, L. [1 ]
Pierres, K. Michel-Le [2 ]
Brasseur, E. [2 ]
Roy, S. [2 ]
le Hecho, I. [3 ]
Larregieu, M. [3 ]
Tellier, S. [3 ]
Potin-Gauder, M. [3 ,4 ]
Boriachon, T. [4 ]
Wazen, P. [4 ]
Diard, A. [4 ]
Belbeze, S. [5 ]
机构
[1] Univ Bordeaux 1, Ctr Phys Mol Opt & Hertzienne, F-33405 Talence, France
[2] Bur Rech Geol & Minieres, Serv MMA, F-45060 Orleans, France
[3] IPREM, CNRS, LCABIE, UMR 5254, F-64053 Pau 9, France
[4] QUANTEL, F-91941 Les Ulis, France
[5] ANTEA, F-45061 Orleans 2, France
关键词
LIBS; In-situ; Polluted soils; Data variability; Sample representativeness;
D O I
10.1016/j.sab.2008.09.008
中图分类号
O433 [光谱学];
学科分类号
0703 ; 070302 ;
摘要
Principal Components Analysis (PCA) is successfully applied to the full laser-induced breakdown spectroscopy (LIBS) spectra of soil samples, defining classes according to the concentrations of the major elements. The large variability of the LIES data is related to the heterogeneity of the samples and the representativeness of the data is finally discussed. Then, the development of a mobile LIBS system dedicated to the in-situ analysis of soils polluted by heavy metals is described. Based on the use of ten-meter long optical fibers, the mobile system allows deported measurements. Finally, the laser-assisted drying process studied by the use of a customized laser has not been retained to overcome the problem of moisture. (C) 2008 Elsevier B.V. All rights reserved.
引用
收藏
页码:1085 / 1090
页数:6
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