LIBS;
In-situ;
Polluted soils;
Data variability;
Sample representativeness;
D O I:
10.1016/j.sab.2008.09.008
中图分类号:
O433 [光谱学];
学科分类号:
0703 ;
070302 ;
摘要:
Principal Components Analysis (PCA) is successfully applied to the full laser-induced breakdown spectroscopy (LIBS) spectra of soil samples, defining classes according to the concentrations of the major elements. The large variability of the LIES data is related to the heterogeneity of the samples and the representativeness of the data is finally discussed. Then, the development of a mobile LIBS system dedicated to the in-situ analysis of soils polluted by heavy metals is described. Based on the use of ten-meter long optical fibers, the mobile system allows deported measurements. Finally, the laser-assisted drying process studied by the use of a customized laser has not been retained to overcome the problem of moisture. (C) 2008 Elsevier B.V. All rights reserved.
机构:
Commissariat Energie Atom Saclay, Nucl Energy Div, Lab Anal Laser & Etud Surface, F-91191 Gif Sur Yvette, FranceCommissariat Energie Atom Saclay, Nucl Energy Div, Lab Anal Laser & Etud Surface, F-91191 Gif Sur Yvette, France
Menut, D
;
Fichet, P
论文数: 0引用数: 0
h-index: 0
机构:
Commissariat Energie Atom Saclay, Nucl Energy Div, Lab Anal Laser & Etud Surface, F-91191 Gif Sur Yvette, FranceCommissariat Energie Atom Saclay, Nucl Energy Div, Lab Anal Laser & Etud Surface, F-91191 Gif Sur Yvette, France
Fichet, P
;
Lacour, JL
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h-index: 0
机构:
Commissariat Energie Atom Saclay, Nucl Energy Div, Lab Anal Laser & Etud Surface, F-91191 Gif Sur Yvette, FranceCommissariat Energie Atom Saclay, Nucl Energy Div, Lab Anal Laser & Etud Surface, F-91191 Gif Sur Yvette, France
Lacour, JL
;
Rivoallan, A
论文数: 0引用数: 0
h-index: 0
机构:
Commissariat Energie Atom Saclay, Nucl Energy Div, Lab Anal Laser & Etud Surface, F-91191 Gif Sur Yvette, FranceCommissariat Energie Atom Saclay, Nucl Energy Div, Lab Anal Laser & Etud Surface, F-91191 Gif Sur Yvette, France
Rivoallan, A
;
Mauchien, P
论文数: 0引用数: 0
h-index: 0
机构:
Commissariat Energie Atom Saclay, Nucl Energy Div, Lab Anal Laser & Etud Surface, F-91191 Gif Sur Yvette, FranceCommissariat Energie Atom Saclay, Nucl Energy Div, Lab Anal Laser & Etud Surface, F-91191 Gif Sur Yvette, France
机构:
Commissariat Energie Atom Saclay, Nucl Energy Div, Lab Anal Laser & Etud Surface, F-91191 Gif Sur Yvette, FranceCommissariat Energie Atom Saclay, Nucl Energy Div, Lab Anal Laser & Etud Surface, F-91191 Gif Sur Yvette, France
Menut, D
;
Fichet, P
论文数: 0引用数: 0
h-index: 0
机构:
Commissariat Energie Atom Saclay, Nucl Energy Div, Lab Anal Laser & Etud Surface, F-91191 Gif Sur Yvette, FranceCommissariat Energie Atom Saclay, Nucl Energy Div, Lab Anal Laser & Etud Surface, F-91191 Gif Sur Yvette, France
Fichet, P
;
Lacour, JL
论文数: 0引用数: 0
h-index: 0
机构:
Commissariat Energie Atom Saclay, Nucl Energy Div, Lab Anal Laser & Etud Surface, F-91191 Gif Sur Yvette, FranceCommissariat Energie Atom Saclay, Nucl Energy Div, Lab Anal Laser & Etud Surface, F-91191 Gif Sur Yvette, France
Lacour, JL
;
Rivoallan, A
论文数: 0引用数: 0
h-index: 0
机构:
Commissariat Energie Atom Saclay, Nucl Energy Div, Lab Anal Laser & Etud Surface, F-91191 Gif Sur Yvette, FranceCommissariat Energie Atom Saclay, Nucl Energy Div, Lab Anal Laser & Etud Surface, F-91191 Gif Sur Yvette, France
Rivoallan, A
;
Mauchien, P
论文数: 0引用数: 0
h-index: 0
机构:
Commissariat Energie Atom Saclay, Nucl Energy Div, Lab Anal Laser & Etud Surface, F-91191 Gif Sur Yvette, FranceCommissariat Energie Atom Saclay, Nucl Energy Div, Lab Anal Laser & Etud Surface, F-91191 Gif Sur Yvette, France