A study on the novel d-f heterodinuclear Gd(III)-Ni(II) cryptate: Synthesis, crystal structure, and magnetic behavior

被引:61
作者
Chen, QY
Luo, QH [1 ]
Zheng, LM
Wang, ZL
Chen, JT
机构
[1] Nanjing Univ, Inst Coordinat Chem, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China
[2] Beijing Univ, State Key Lanthanide Mat Chem, Beijing 100008, Peoples R China
[3] FuZhou State Key Lab Struct Chem, Fuzhou 350002, Peoples R China
关键词
D O I
10.1021/ic010270y
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A novel d-f heterodinuclear Gd(III)-Ni(II) cryptate was synthesized by a stepwise method using the mononuclear Gd(III) cryptate as precursor. A quantitative analysis shows that the Gd(M)-Ni(II) interaction is of the ferromagnetic type.
引用
收藏
页码:605 / +
页数:6
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