Nano-cellular carbon current collectors with stable cyclability for Li-S batteries

被引:70
作者
Chung, Sheng-Heng
Manthiram, Arumugam [1 ]
机构
[1] Univ Texas Austin, Electrochem Energy Lab, Austin, TX 78712 USA
关键词
LITHIUM-SULFUR BATTERY; CATHODE; PERFORMANCE; POLYSULFIDES; DISCHARGE; IMPROVE;
D O I
10.1039/c3ta11819c
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Li-S batteries have been investigated with a simple modification of the electrode configuration by applying a nano-cellular carbon current collector (NC current collector). This micro-meso-macroporous electrode is composed of interwoven carbon fibers with the carbon nanofoam firmly attached to them. The nanofoam plate functions as a reservoir to store the active material and localize the dissolved polysulfides, stabilizing the electrochemical reaction within the cathode region. As a result, the NC current collector offers a considerably high discharge capacity and superior cycle stability.
引用
收藏
页码:9590 / 9596
页数:7
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