Influence of microstructure on the capacitive performance of polyaniline/carbon nanotube array composite electrodes

被引：139

作者：

Zhang, Hao ^{[1
]}

Cao, Gaoping ^{[1
]}

Wang, Weikun ^{[1
]}

Yuan, Keguo ^{[1
]}

Xu, Bin ^{[1
]}

Zhang, Wenfeng ^{[1
]}

Cheng, Jie ^{[1
]}

Yang, Yusheng ^{[1
]}

机构：

[1] Res Inst Chem Def, Beijing 100083, Peoples R China

来源：

ELECTROCHIMICA ACTA | 2009年 / 54卷 / 04期

基金：

中国国家自然科学基金;

关键词：

Electrodeposition; Carbon nanotube array; Microstructure; Polyaniline; Supercapacitors; ELECTROCHEMICAL PROPERTIES; MESOPOROUS NANOCOMPOSITE; CARBON; STORAGE; ENERGY; BEHAVIOR; SURFACE; DESIGN; ROUTE;

D O I：

10.1016/j.electacta.2008.09.004

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

A series of polyaniline/carbon nanotube array (PANI/CNTA) composite electrodes are prepared by electrodeposition of PANI onto CNTA electrodes by 100-500 cyclic voltammetry (CV) cycles, with the aim to investigate the influence of microstructure on the capacitive performance of PANI/CNTA composites. The morphology of PANI/CNTA composites varies remarkably with the CV cycles of electrodeposition. The optimum condition is obtained for the PANI/CNTA composite prepared by 100 CV cycles, corresponding to the highest specific capacitance, best rate performance, and longest cycle life, which are much better than that of activated carbon fiber cloth, the PANI electrodeposited on stainless steel substrate, and CNTA electrode. The forming process of the microstructure and its influence on the capacitive performance of PANI/CNTA composites are presented in this paper. (C) 2008 Elsevier Ltd. All rights reserved.

引用

页码：1153 / 1159

页数：7

共 36 条

[11] Influence of the microstructure on the supercapacitive behavior of polyaniline/single-wall carbon nanotube composites [J].