Salts of C60(OH)8 Electrodeposited onto a Glassy Carbon Electrode: Surprising Catalytic Performance in the Hydrogen Evolution Reaction

被引：96

作者：

Zhuo, Junqiao ^{[1
]}

Wang, Tanyuan ^{[1
]}

Zhang, Gang ^{[2
]}

Liu, Lu ^{[1
]}

Gan, Liangbing ^{[2
,3
]}

Li, Meixian ^{[1
]}

机构：

[1] Peking Univ, Coll Chem & Mol Engn, Beijing 100871, Peoples R China

[2] Chinese Acad Sci, Inst Chem, CSA Key Lab Organ Solids, Beijing Natl Lab Mol Sci, Beijing 100080, Peoples R China

[3] Peking Univ, Coll Chem & Mol Engn, Key Lab Bioorgan Chem & Mol Engn, Minist Educ, Beijing 100871, Peoples R China

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 41期

关键词：

electrocatalysis; electrodeposition; fullerenes; hydrogen evolution reaction; FULLERENE DERIVATIVES; RECENT PROGRESS; MOS2; WATER; ACID; NI; NANOPARTICLES; EFFICIENT; FILMS; C-60;

D O I：

10.1002/anie.201305328

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Full(erene) of surprises: The first isomerically pure multi-hydroxylated fullerene, C60(OH)8, shows a reduction peak and a reoxidation peak in aqueous solution. With surprising catalytic performance in the hydrogen evolution reaction (HER), when electrodeposited on a glassy carbon electrode (GCE), salts of C60(OH)8 may prove to be effective molecular catalysts for conducting the HER without transition metals. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：10867 / 10870

页数：4