Introduction of two benzyl groups to C-60 by using the Collman reagent

被引：34

作者：

Miki, S

Kitao, M

Fukunishi, K

机构：

[1] Dept. of Chem. and Mat. Technology, Kyoto Institute of Technology, Kyoto 606, Matsugasaki, Sakyo-ku

来源：

TETRAHEDRON LETTERS | 1996年 / 37卷 / 12期

关键词：

D O I：

10.1016/0040-4039(96)00215-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Addition of C-60 to a suspension of the Collman reagent in THF gave a strongly colored but almost transparent solution. Treatment of the resulting solution with benzyl bromide gave a C-60 derivative possessing two benzyl groups. The H-1-NMR as well as the C-13-NMR of the product indicated that the reaction site was 1,4-position.

引用

页码：2049 / 2052

页数：4

共 17 条

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