Photoreactions of silyliron(II) complexes Cp'Fe(CO)(2)SiMe(3) (Cp'=eta(5)-C5H5, eta(5)-C(5)Me(5)) with di-p-tolylgermane (p-Tol)(2)GeH2

被引：10

作者：

ElMaradny, A ^{[1
]}

Tobita, H ^{[1
]}

Ogino, H ^{[1
]}

机构：

[1] TOHOKU UNIV, GRAD SCH SCI, DEPT CHEM, SENDAI, MIYAGI 98077, JAPAN

来源：

CHEMISTRY LETTERS | 1996年 / 01期

关键词：

D O I：

10.1246/cl.1996.83

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Photolysis of CpFe(CO)(2)SiMe(3) (Cp = eta(5)-C5H5) in the presence of (p-Tol)(2)GeH2 afforded a mixture of cis and trans isomers of diiron complexes Cp(2)Fe(2)(CO)(2)(mu-CO){mu-Ge(p-Tol)(2)} and Cp(2)Fe(2)(CO)(2){mu-Ge(p-Tol)(2)}(2). The photostationary state with cis : trans = 85 : 15 was attained by the photolysis of either cis or trans isomer of the latter complex. In contrast, photoreaction of Cp*Fe(CO)(2)SiMe(3) (Cp* = eta(5)-C(5)Me(5)) with (p-Tol)(2)GeH2 gave a monoiron complex Cp*Fe(CO)(2)GeH(p- Tol)(2).

引用

页码：83 / 84

页数：2

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