Linking of metal centres through boryl ligands: synthesis, spectroscopic and structural characterisation of symmetrically bridged boryl complexes

被引:22
作者
Aldridge, S
Calder, RJ
Rossin, A
Dickinson, AA
Willock, DJ
Jones, C
Evans, DJ
Steed, JW
Light, EM
Coles, SJ
Hursthouse, MB
机构
[1] Cardiff Univ, Dept Chem, Cardiff CF10 3TB, S Glam, Wales
[2] John Innes Ctr Plant Sci Res, Dept Biol Chem, Norwich NR4 7UH, Norfolk, England
[3] Kings Coll London, Dept Chem, London WC2R 2LS, England
[4] Univ Southampton, Dept Chem, Southampton SO17 1BJ, Hants, England
来源
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 2002年 / 09期
关键词
D O I
10.1039/b200695m
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Dinuclear species containing iron centres linked via various bridging boryl ligands have been synthesised and a combination of crystallographic, computational and spectroscopic (Mossbauer, IR, Raman) techniques have been used to probe the bonding in these complexes.
引用
收藏
页码:2020 / 2026
页数:7
相关论文
共 61 条
  • [1] Synthesis and reactivity of transition metal complexes containing halogenated boryl ligands
    Aldridge, S
    Calder, RJ
    Baghurst, RE
    Light, ME
    Hursthouse, MB
    [J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2002, 649 (1-2) : 9 - 14
  • [2] Convenient syntheses, spectroscopic and structural characterisation of bi-functional boranes
    Aldridge, S
    Calder, RJ
    Cunningham, MH
    Malik, KMA
    Steed, JW
    [J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2000, 614 : 188 - 194
  • [3] Perfluoroaryl boryl complexes: synthesis, spectroscopic and structural characterisation of a complex containing the bis(pentafluorophenyl)boryl ligand
    Aldridge, S
    Al-Fawaz, A
    Calder, RJ
    Dickinson, AA
    Willock, DJ
    Light, ME
    Hursthouse, MB
    [J]. CHEMICAL COMMUNICATIONS, 2001, (18) : 1846 - 1847
  • [4] Linking of metal centres through boryl ligands:: synthesis, spectroscopic and structural characterisation of a symmetrically bridged boryl complex CpFe(CO)2BO2C6H2O2BFe(CO)2Cp
    Aldridge, S
    Calder, RJ
    Dickinson, AA
    Willock, DJ
    Steed, JW
    [J]. CHEMICAL COMMUNICATIONS, 2000, (15) : 1377 - 1378
  • [5] Hydroborations catalysed by transition metal complexes
    Beletskaya, I
    Pelter, A
    [J]. TETRAHEDRON, 1997, 53 (14) : 4957 - 5026
  • [6] Transition metal complexes of boron - synthesis, structure and reactivity
    Braunschweig, H
    Colling, M
    [J]. COORDINATION CHEMISTRY REVIEWS, 2001, 223 : 1 - 51
  • [7] Braunschweig H, 1998, EUR J INORG CHEM, P291
  • [8] Diboran(4)yl groups as ligands to transition metals
    Braunschweig, H
    Ganter, B
    Koster, M
    Wagner, T
    [J]. CHEMISCHE BERICHTE, 1996, 129 (09) : 1099 - 1101
  • [9] Braunschweig H, 1999, EUR J INORG CHEM, P1523
  • [10] Braunschweig H, 1998, EUR J INORG CHEM, P465