Fast proton conductivity: A phenomenon between the solid and the liquid state?

被引：136

作者：

Kreuer, KD

机构：

[1] Max-Planck-Inst fuer, Festkoerperforschung, Stuttgart, Germany

来源：

SOLID STATE IONICS | 1997年 / 94卷 / 1-4期

关键词：

proton conductivity; Grotthuss mechanism; hydrogen bonding; water; CsHSO4; H2O; H3PO4; NH3C3N2H4 (imidazole);

D O I：

10.1016/S0167-2738(96)00608-X

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

After the compilation of some general observations on the formation and mobility of protonic charge carriers in solids and liquids, proton conductivity in CsHSO4 and water is discussed in some detail. Proton conductivity is interpreted as a phenomenon between the solid and the liquid state characterized by the structural and dynamic disorder of a hydrogen bond 'network'. Structural and chemical criteria for the appearance of high proton conductivity are formulated.

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页码：55 / 62

页数：8

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