Influence of CdCl2 treatment on structural and optical properties of vacuum evaporated CdTe thin films

被引:44
作者
Lalitha, S [1 ]
Sathyamoorthy, R [1 ]
Senthilarasu, S [1 ]
Subbarayan, A [1 ]
机构
[1] Kongunadu Arts & Sci Coll, R&D Dept Phys, Coimbatore 29, Tamil Nadu, India
关键词
CdTe; CdCl2; treatment; optical band gap; thin films;
D O I
10.1016/j.solmat.2005.04.006
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
In this article we have discussed the structural, optical properties of vacuum evaporated CdTe thin films before and after CdCl2 treatment. The CdTe thin films were prepared by vacuum evaporation. Films were prepared under the vacuum of 10(-6) Torr. The structural studies have been performed by the X-ray diffraction (XRD) technique. The XRD analysis of vacuum evaporated CdTe films reveals that the structure of films is polycrystalline in nature. However, the crystallinity has been improved after the CdCl2, treatment as shown by an increase of the diffraction peak intensities. This is due to the enhancement in the atomic mobility of CdTe. The optical properties of the CdTe thin films have been studied by the spectrophotometer in the 300-800 nm wavelength range. It is observed that the optical band gap energy is highly dependent on CdCl2, treatments. The optical transitions in these films are found to be direct and allowed. (c) 2005 Elsevier B.V. All rights reserved.
引用
收藏
页码:694 / 703
页数:10
相关论文
共 52 条
[21]   Characterization of CdTe thin film - dependence of structural and optical properties on temperature and thickness [J].
Lalitha, S ;
Sathyamoorthy, R ;
Senthilarasu, S ;
Subbarayan, A ;
Natarajan, K .
SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2004, 82 (1-2) :187-199
[22]   Electrical and optical properties of CdTe films prepared by vacuum evaporation with close spacing between source and substrate [J].
Lee, JH ;
Lim, DG ;
Yi, JS .
SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2003, 75 (1-2) :235-242
[23]   Micro through nanostructure investigations of polycrystalline CdTe: Correlations with processing and electronic structures [J].
Levi, DH ;
Moutinho, HR ;
Hasoon, FS ;
Keyes, BM ;
Ahrenkiel, RK ;
AlJassim, M ;
Kazmerski, LL ;
Birkmire, RW .
SOLAR ENERGY MATERIALS AND SOLAR CELLS, 1996, 41-2 :381-393
[24]   Transmission electron microscopy of CdTe/CdS based solar cells [J].
Loginov, YY ;
Durose, K ;
AlAllak, HM ;
Galloway, SA ;
Oktik, S ;
Brinkman, AW ;
Richter, H ;
Bonnet, D .
JOURNAL OF CRYSTAL GROWTH, 1996, 161 (1-4) :159-163
[25]  
LOPEZOTERO A, 1977, J CRYST GROWTH, V42, P157, DOI 10.1016/0022-0248(77)90189-0
[26]   Structural and opto-electronic properties of electrodeposited CdTe on stainless steel foil [J].
Mathew, X ;
Sebastian, PJ ;
Sanchez, A ;
Campos, J .
SOLAR ENERGY MATERIALS AND SOLAR CELLS, 1999, 59 (1-2) :99-114
[27]   Temperature dependence of the optical transitions in CdTe thin film - Investigation with photoresponse spectra [J].
Mathew, X ;
Enriquez, JP .
SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2000, 63 (04) :347-354
[28]   Optical properties of electrodeposited CdTe thin films [J].
Mathew, X ;
Sebastian, PJ .
SOLAR ENERGY MATERIALS AND SOLAR CELLS, 1999, 59 (1-2) :85-98
[29]   Does the band gap calculated from the photocurrent of Schottky devices lead to erroneous results? Analysis for CdTe [J].
Mathew, X .
JOURNAL OF PHYSICS D-APPLIED PHYSICS, 2000, 33 (13) :1565-1571
[30]   CdTe/CdS solar cells on flexible substrates [J].
Mathew, X ;
Enriquez, JP ;
Romeo, A ;
Tiwari, AN .
SOLAR ENERGY, 2004, 77 (06) :831-838