Metal-organic frameworks constructed from pentagonal antiprismatic and cuboctahedral secondary building units

被引：148

作者：

Vodak, DT ^{[1
]}

Braun, ME ^{[1
]}

Kim, J ^{[1
]}

Eddaoudi, M ^{[1
]}

Yaghi, OM ^{[1
]}

机构：

[1] Univ Michigan, Dept Chem, Mat Design & Discovery Grp, Ann Arbor, MI 48109 USA

来源：

CHEMICAL COMMUNICATIONS | 2001年 / 24期

关键词：

D O I：

10.1039/b108684g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two crystalline metal-organic frameworks formulated as Zn-6(NDC)(5)(OH)(2)(DMT)(2). 4DMF, MOF-48, and Zn-7(m-BDC)(6)(OH)(4)(H2O)(2). 6DMF . 4H(2)O, MOF-49, (NDC = 1,4-naphthalenedicarboxylate; m-BDC = 1,3-benzenedicarboxylate) have been synthesized and fully characterized by single crystal X-ray diffraction studies, which reveal that the frameworks are constructed from pentagonal antiprismatic (MOF-48) and cuboctahedral (MOF-49) secondary building units respectively, however, both are reticulated into 3-D structures having the B network of CaB6.

引用

页码：2534 / 2535

页数：2

共 17 条

[1] Three-dimensional open frameworks based on cobalt(II) and nickel(II) m-pyridinecarboxylates [J].

Ayyappan, P ;

Evans, OR ;

Lin, WB .

INORGANIC CHEMISTRY, 2001, 40 (18) :4627-4632

[2] VAN DER WAALS VOLUMES + RADII [J].

BONDI, A .

JOURNAL OF PHYSICAL CHEMISTRY, 1964, 68 (03) :441-+

[3]

Bourne SA, 2001, ANGEW CHEM INT EDIT, V40, P2111, DOI 10.1002/1521-3773(20010601)40:11<2111::AID-ANIE2111>3.0.CO

[4]

2-F

[5] Tertiary building units: Synthesis, structure, and porosity of a metal-organic dendrimer framework (MODF-1) [J].

Chae, HK ;

Eddaoudi, M ;

Kim, J ;

Hauck, SI ;

Hartwig, JF ;

O'Keeffe, M ;

Yaghi, OM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (46) :11482-11483

[6] Interwoven metal-organic framework on a periodic minimal surface with extra-large pores [J].

Chen, BL ;

Eddaoudi, M ;

Hyde, ST ;

O'Keeffe, M ;

Yaghi, OM .

SCIENCE, 2001, 291 (5506) :1021-1023

[7] Cu2(ATC)•6H2O:: Design of open metal sites in porous metal-organic crystals (ATC:1,3,5,7-adamantane tetracarboxylate) [J].

Chen, BL ;

Eddaoudi, M ;

Reineke, TM ;

Kampf, JW ;

O'Keeffe, M ;

Yaghi, OM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (46) :11559-11560

[8] CRYSTAL-STRUCTURES OF 3 BASIC ZINC CARBOXYLATES TOGETHER WITH INFRARED AND FAB MASS-SPECTROMETRY STUDIES IN SOLUTION [J].

CLEGG, W ;

HARBRON, DR ;

HOMAN, CD ;

HUNT, PA ;

LITTLE, IR ;

STRAUGHAN, BP .

INORGANICA CHIMICA ACTA, 1991, 186 (01) :51-60

[9] Modular chemistry: Secondary building units as a basis for the design of highly porous and robust metal-organic carboxylate frameworks [J].

Eddaoudi, M ;

Moler, DB ;

Li, HL ;

Chen, BL ;

Reineke, TM ;

O'Keeffe, M ;

Yaghi, OM .

ACCOUNTS OF CHEMICAL RESEARCH, 2001, 34 (04) :319-330

[10] Synthesis, crystal structure and solution behavior of a novel tetranuclear Zn(II) Schiff base complex [J].

Hermann, J ;

Erxleben, A .

INORGANICA CHIMICA ACTA, 2000, 304 (01) :125-129

← 1 2 →