Edible catalysts for clean chemical reactions: Bioreduction of aromatic ketones and biooxidation of secondary alcohols using plants

被引：66

作者：

Andrade, LH ^{[1
]}

Utsunomiya, RS ^{[1
]}

Omori, AT ^{[1
]}

Porto, ALM ^{[1
]}

Comasseto, JV ^{[1
]}

机构：

[1] Univ Sao Paulo, Inst Quim, Lab Quim Fina & Biocatalise, BR-05508900 Sao Paulo, Brazil

来源：

JOURNAL OF MOLECULAR CATALYSIS B-ENZYMATIC | 2006年 / 38卷 / 02期

基金：

巴西圣保罗研究基金会;

关键词：

biotransformation; biooxidation; bioreduction; plants; root; ketone; alcohol;

D O I：

10.1016/j.molcatb.2005.11.009

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

Bioreduction of acetophenone derivatives 1a-e and biooxidation of (RS)-1-phenylethanol derivatives 2a-e have been evaluated using edible plants as biocatalysts. Chiral (R)- and (S)-alcohols were prepared by different plants in up to 98% of enantiomeric excess. Ketones can also be prepared from alcohol oxidation using this clean protocol. (c) 2005 Elsevier B.V. All rights reserved.

引用

页码：84 / 90

页数：7

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