Alkyne coupling reactions mediated by iron(II) complexes:: Highly chemo- and regioselective formation of η6-coordinated arene and pyridine complexes

被引：41

作者：

Ferré, K

Toupet, L

Guerchais, V

机构：

[1] Univ Rennes 1, Inst Chim Rennes, CNRS, UMR 6509, F-35042 Rennes, France

[2] Univ Rennes 1, Grp Matiere Condensee, CNRS, UMR 6626, F-35042 Rennes, France

来源：

ORGANOMETALLICS | 2002年 / 21卷 / 13期

关键词：

D O I：

10.1021/om0201967

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of the bis(acetonitrile) complex 1 with HCequivalent toCPh affords the (allyl)carbene complex 3, which results from a head-to-tail coupling of two alkynes. The tris(acetonitrile) complex [Fe(C5Me5)(CH3CN)(3)][PF6] (2) mediates highly chemo- and regioselectiue [2 + 2 + 2] cycloaddition reactions of Cequivalent toC and Cequivalent toN triple bonds, providing access to pi-arene and -pyridine complexes. The pyridine complex 5a has been characterized by an X-ray crystal structure.

引用

页码：2578 / 2580

页数：3

共 26 条

[21]

2-G

[22] COBALT-MEDIATED [2+2+2]-CYCLOADDITIONS - A MATURING SYNTHETIC STRATEGY [J].