Supported metalloporphyrin catalysts for alkene epoxidation

被引：59

作者：

Brulé, E

de Miguel, YR

机构：

[1] Univ Paris 06, Lab Synthese Organ & Organomet, F-75252 Paris 05, France

[2] LABEIN, Bizkaia 48160, Spain

来源：

ORGANIC & BIOMOLECULAR CHEMISTRY | 2006年 / 4卷 / 04期

关键词：

D O I：

10.1039/b509985d

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

This review is devoted to the recent advances in the preparation of immobilised metalloporphyrins and their use as heterogeneous catalysts for alkene epoxidation. The wide range of supports, nature of attachments, and metalloporphyrins that have been reported is detailed and a comparison is made between the activities of the resulting catalysts in the epoxidation of different alkenes. The important issue of recyclability of the metalloporphyrins is also covered.

引用

页码：599 / 609

页数：11

共 77 条

[1]

Assis MD, 1998, J CHEM SOC PERK T 2, P2221

[2]

AZENBACHER P, 1995, J MOL CATAL A-CHEM, V96, P311

[3]

AZENBACHER P, 1997, J MOL CTAL A, V118, P63

[4]

BARLOY L, 1992, NEW J CHEM, V16, P71