Supported metalloporphyrin catalysts for alkene epoxidation

被引：59

作者：

Brulé, E

de Miguel, YR

机构：

[1] Univ Paris 06, Lab Synthese Organ & Organomet, F-75252 Paris 05, France

[2] LABEIN, Bizkaia 48160, Spain

来源：

ORGANIC & BIOMOLECULAR CHEMISTRY | 2006年 / 4卷 / 04期

关键词：

D O I：

10.1039/b509985d

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

This review is devoted to the recent advances in the preparation of immobilised metalloporphyrins and their use as heterogeneous catalysts for alkene epoxidation. The wide range of supports, nature of attachments, and metalloporphyrins that have been reported is detailed and a comparison is made between the activities of the resulting catalysts in the epoxidation of different alkenes. The important issue of recyclability of the metalloporphyrins is also covered.

引用

收藏

页码：599 / 609

页数：11

相关论文

共 77 条

[41]

Mirkhani V, 2000, J CHEM RES, P515

[42] Polystyrene encapsulation of manganese porphyrins: highly efficient catalysts for oxidation of olefins [J].

Naik, R ;

Joshi, P ;

Umbarkar, S ;

Deshpande, RK .

CATALYSIS COMMUNICATIONS, 2005, 6 (02) :125-129

[43] SYNTHESIS AND CATALYTIC CAPABILITY OF ZEOLITE-ENCAPSULATED IRON AND MANGANESE TETRAMETHYLPORPHINE COMPLEXES [J].

NAKAMURA, M ;

TATSUMI, T ;

TOMINAGA, H .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1990, 63 (11) :3334-3336

[44] New insights into the mechanisms of O-O bond cleavage of hydrogen peroxide and tert-alkyl hydroperoxides by iron(III) porphyrin complexes [J].

Nam, W ;

Han, HJ ;

Oh, SY ;

Lee, YJ ;

Choi, MH ;

Han, SY ;

Kim, C ;

Woo, SK ;

Shin, W .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (36) :8677-8684

[45] Manganese porphyrins incorporated in polydimethylsiloxane membranes: selective catalysts for the epoxidation of deactivated alkenes [J].

Neys, PEF ;

Severeyns, A ;

Vankelecom, IFJ ;

Ceulemans, E ;

Dehaen, W ;

Jacobs, PA .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 1999, 144 (02) :373-377

[46] Oxidation of cyclohexene over Mn(TMPyP) porphyrin-exchanged Al,Si-mesoporous molecular sieves [J].

Poltowicz, J ;

Serwicka, EM ;

Bastardo-Gonzalez, E ;

Jones, W ;

Mokaya, R .

APPLIED CATALYSIS A-GENERAL, 2001, 218 (1-2) :211-217

[47] Characterization and catalytic activity of iron(III) mono(4-N-methyl pyridyl)-tris(halophenyl) porphyrins in homogeneous and heterogeneous systems [J].

Prado-Manso, CMC ;

Vidoto, EA ;

Vinhado, FS ;

Sacco, HC ;

Ciuffi, KJ ;

Martins, PR ;

Ferreira, AG ;

Lindsay-Smith, JR ;

Nascimento, OR ;

Iamamoto, Y .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 1999, 150 (1-2) :251-266

[48] POROUS, POLYMER-BONDED METALLOPORPHYRINS [J].

ROLLMANN, LD .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1975, 97 (08) :2132-2136

[49] Enantioselective epoxidation of olefins with chiral metalloporphyrin catalysts [J].

Rose, E ;

Andrioletti, B ;

Zrig, S ;

Quelquejeu-Ehtève, M .

CHEMICAL SOCIETY REVIEWS, 2005, 34 (07) :573-583

[50] Alkene epoxidation with iodosylbenzene catalysed by polyionic manganese porphyrins electrostatically bound to counter-charged supports [J].

Sacco, HC ;

Iamamoto, Y ;

Smith, JRL .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 2001, (02) :181-190

← 1 2 3 4 5 6 7 8 →