Supported metalloporphyrin catalysts for alkene epoxidation

被引:59
作者
Brulé, E
de Miguel, YR
机构
[1] Univ Paris 06, Lab Synthese Organ & Organomet, F-75252 Paris 05, France
[2] LABEIN, Bizkaia 48160, Spain
关键词
D O I
10.1039/b509985d
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
This review is devoted to the recent advances in the preparation of immobilised metalloporphyrins and their use as heterogeneous catalysts for alkene epoxidation. The wide range of supports, nature of attachments, and metalloporphyrins that have been reported is detailed and a comparison is made between the activities of the resulting catalysts in the epoxidation of different alkenes. The important issue of recyclability of the metalloporphyrins is also covered.
引用
收藏
页码:599 / 609
页数:11
相关论文
共 77 条
[51]  
SATO Y, 1986, CHEM PHARM BULL, V34, P2885
[52]   Catalytic activity of nitro- and carboxy-substituted iron porphyrins in hydrocarbon oxidation - Homogeneous solution and supported systems [J].
Schiavon, MA ;
Iamamoto, Y ;
Nascimento, OR ;
Assis, MD .
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2001, 174 (1-2) :213-222
[53]  
Shin JY, 1998, B KOR CHEM SOC, V19, P875
[54]  
Smith J. R. L., 1994, METALLOPORPHYRINS CA, P350
[55]   Manganese(III) porphyrin supported on polystyrene as a heterogeneous alkene epoxidation and alkane hydroxylation catalyst [J].
Tangestaninejad, S ;
Habibi, MH ;
Mirkhani, V ;
Moghadam, M .
SYNTHETIC COMMUNICATIONS, 2002, 32 (21) :3331-3337
[56]   Efficient olefin epoxidation and alkane hydroxylation using sulfonated manganese(III) porphyrin supported on IRA-900 ion-exchange resin [J].
Tangestaninejad, S ;
Moghadam, M .
SYNTHETIC COMMUNICATIONS, 1998, 28 (03) :427-432
[57]  
Tangestaninejad S, 2001, J CHEM RES, P444
[58]   Polystyrene-bound manganese(III) porphyrin as a heterogeneous catalyst for alkene epoxidation [J].
Tangestaninejad, S ;
Mirkhani, V .
JOURNAL OF CHEMICAL RESEARCH-S, 1998, (12) :788-789
[59]   Alkene epoxidation and alkane hydroxylation with periodate catalysed by manganese(III) porphyrin supported on poly(4-vinylpyridine) [J].
Tangestaninejad, S ;
Moghadam, M .
JOURNAL OF CHEMICAL RESEARCH-S, 1998, (05) :242-+
[60]   Efficient and selective epoxidation of alkenes with sodium periodate using supported manganese porphyrins under ultrasonic irradiation [J].
Tangestaninejad, S ;
Mirkhani, V .
CHEMISTRY LETTERS, 1998, (12) :1265-1266