Unique uranium(III) cations anchored by polydentate sulfur-based ligands:: Synthesis and structure of [U{ H(R)B(timMe)2}2(THF)3][BPh4] (R = H, Ph)

被引：35

作者：

Maria, L ^{[1
]}

Domingos, A ^{[1
]}

Santos, I ^{[1
]}

机构：

[1] ITN, Dept Quim, P-2686953 Sacavem, Portugal

来源：

INORGANIC CHEMISTRY | 2001年 / 40卷 / 27期

关键词：

D O I：

10.1021/ic0106827

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reactions of bis(2-mercapto- 1 -methylimidazolyl)-borates ([H(R)B(tim(Me))(2)](-), R = H and Ph) with [UI3-(THF)(4)] and TI[BPh4] in tetrahydrofuran gave, in good yield, [U{H(R)B(tim(Me))(2)}(2)(THF)(3)][BPh4] (R = H (1), R = Ph (2)), Complexes I and 2 are rare examples of U(III)) cations and unprecedented examples of f elements anchored by sulfur-based polydentate ligands.

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页码：6863 / +

页数：3

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