Microwave assisted, highly efficient solid state N- and S-alkylation

被引：12

作者：

Jaisinghani, HG ^{[1
]}

Khadilkar, BM ^{[1
]}

机构：

[1] Univ Bombay, Dept Chem Technol, Bombay 400019, Maharashtra, India

来源：

SYNTHETIC COMMUNICATIONS | 1999年 / 29卷 / 21期

关键词：

D O I：

10.1080/00397919908086007

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Secondary amines and thiophenols were alkylated with alkyl and benzyl halides rapidly on alumina supported potassium carbonate under solvent-free conditions using microwaves. Equimolar amounts of the secondary amine/thiophenol and alkyl halide were used. The procedure neither required any strong base nor a PTC. Aniline was also monobenzylated with benzylchloride. Separation of the products from the reactants was very simple by using a nonpolar solvent for desorption.

引用

页码：3693 / 3698

页数：6