Synthesis of ruthenium(II) 1,2,3-trimethylindenyl complexes: X-ray crystal structure of [Ru(=C=C=CPh2)(eta(5)-1,2,3-Me3C9H4)(CO)(PPh3)][BF4]

被引：61

作者：

Gamasa, MP

Gimeno, J

GonzalezBernardo, C

Borge, J

GarciaGranda, S

机构：

[1] UNIV OVIEDO,FAC QUIM,INST QUIM ORGANOMET ENRIQUE MOLES,DEPT QUIM ORGAN & INORGAN,E-33071 OVIEDO,SPAIN

[2] UNIV OVIEDO,FAC QUIM,INST QUIM ORGANOMET ENRIQUE MOLES,DEPT QUIM FIS & ANALIT,E-33071 OVIEDO,SPAIN

来源：

ORGANOMETALLICS | 1997年 / 16卷 / 12期

关键词：

D O I：

10.1021/om970154w

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The first ruthenium(II) 1,2,3-trimethylindenyl complexes have been prepared, including allenylidene, alkynyl, and alkenylcarbene derivatives. The X-ray crystal structure of [Ru(=C=C=CPh2)(eta(5)-1,2,3-Me3C9H4)(CO)(PPh3)] [BF4] is described.

引用

页码：2483 / 2485

页数：3

共 22 条

[1] ACYCLIC CP(CO)2FE DISUBSTITUTED ETA-1-VINYLIDENE-ETA-2-ACETYLENE ISOMERIZATIONS
BLY, RS
ZHONG, ZD
KANE, C
BLY, RK
[J]. ORGANOMETALLICS, 1994, 13 (03) : 899 - 905
[2] Borge J., UNPUB
[3] BORGE J, COMMUNICATION
[4] ALLENYLIDENE INDENYL RUTHENIUM(II) COMPLEXES AS SOURCES OF HIGHLY FUNCTIONALIZED ALKYNYL COMPLEXES - SYNTHESIS OF THE FIRST, BIMETALLIC DERIVATIVES CONTAINING A VINYLIDENE-CARBENE BRIDGE
CADIERNO, V
GAMASA, MP
GIMENO, J
BORGE, J
GARCIAGRANDA, S
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (21) : 2495 - 2496
[5] REACTIONS OF NOVEL CATIONIC DIPHENYLALLENYLIDENE COMPLEXES [RU(=C=C=CPH2)L2(ETA-C9H7)]+ (L = PPH3 L2 = BIS(DIPHENYLPHOSPHINO)METHANE, DPPM OR 1,2-BIS(DIPHENYLPHOSPHINO)ETHANE, DPPE) WITH NEUTRAL AND ANIONIC NUCLEOPHILES
CADIERNO, V
GAMASA, MP
GIMENO, J
LASTRA, E
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1994, 474 (1-2) : C27 - C29
[6] Activation of 2-propyn-1-ol derivatives by indenylruthenium(II) and -osmium(II) complexes: X-ray crystal structures of the allenylidene complexes [M(=C=C=CPh(2))(eta(5)-C9H7)(PPh(3))(2)][PF6]center dot CH2Cl2 (M=Ru, Os) and EHMO calculations
Cadierno, V
Gamasa, MP
Gimeno, J
GonzalezCueva, M
Lastra, E
Borge, J
GarciaGranda, S
PerezCarreno, E
[J]. ORGANOMETALLICS, 1996, 15 (08) : 2137 - 2147
[7] AN UNPRECEDENTED RUTHENIUM ALLENYLIDENE COMPLEX CONTAINING AN UNSATURATED BICYCLIC SYSTEM - FORMAL ADDITION OF 1-ETHYNYL-1-CYCLOHEXANOL TO AN ALKENYLVINYLIDENE INTERMEDIATE COMPLEX
CADIERNO, V
GAMASA, MP
GIMENO, J
LASTRA, E
BORGE, J
GARCIAGRANDA, S
[J]. ORGANOMETALLICS, 1994, 13 (03) : 745 - 747
[8] A GENERAL-ROUTE TO SANDWICH AND HALF-SANDWICH TITANIUM IMIDO COMPLEXES - X-RAY STRUCTURE OF [TI(ETA(4)-ME(8)TAA)(NBU(T))] (ME(4)TAA=TETRAMETHYLDIBENZOTETRAAZA[14]ANNULENE)
DUNN, SC
BATSANOV, AS
MOUNTFORD, P
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (17) : 2007 - 2008
[9] Five-coordinate complex [RuHCl(CO)(PPr3i)(2)] as a precursor for the preparation of new cyclopentadienylruthenium compounds containing unsaturated eta(1)-carbon ligands
Esteruelas, MA
Gomez, AV
Lahoz, FJ
Lopez, AM
Onate, E
Oro, LA
[J]. ORGANOMETALLICS, 1996, 15 (15) : 3423 - 3435
[10] ELECTRONIC-STRUCTURE AND PHOTOELECTRON-SPECTROSCOPY OF D(8) RHODIUM INDENYL COMPLEXES
FRANKCOM, TM
GREEN, JC
NAGY, A
KAKKAR, AK
MARDER, TB
[J]. ORGANOMETALLICS, 1993, 12 (09) : 3688 - 3697

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