Synthesis and crystal structure of Li[{Ca7(μ3-OH)8I6(thf)12}2(μ-I)]•3THF, a unique H-bound dimer of a Ca7-cluster on the way to sol-gels

被引：37

作者：

Fromm, KM ^{[1
]}

机构：

[1] Univ Geneva, CH-1211 Geneva 4, Switzerland

来源：

CHEMICAL COMMUNICATIONS | 1999年 / 17期

关键词：

D O I：

10.1039/a904560k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In analogy to transition metal clusters, a mixed ligand Ca-cluster, consisting of two Ca-7-units linked via H-bonds, has been synthesised and structurally characterised, its thermal decomposition leading to the formation of sol-gels is also described.

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页码：1659 / 1660

页数：2

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