Asymmetric synthesis of a rigid diphosphine ligand containing two phosphorus and four carbon stereogenic centres by means of a chiral palladium complex promoted Diels-Alder reaction

被引：33

作者：

Leung, PH ^{[1
]}

Selvaratnam, S ^{[1
]}

Cheng, CR ^{[1
]}

Mok, KF ^{[1
]}

Rees, NH ^{[1
]}

McFarlane, W ^{[1
]}

机构：

[1] UNIV NEWCASTLE UPON TYNE, DEPT CHEM, NEWCASTLE UPON TYNE NE1 7RU, TYNE & WEAR, ENGLAND

来源：

CHEMICAL COMMUNICATIONS | 1997年 / 08期

关键词：

PHOSPHINES; ROUTE;

D O I：

10.1039/a700314e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An optically pure diphosphine ligand containing two phosphorus and four carbon stereogenic centres is prepared efficiently by a chiral organopalladium complex promoted asymmetric Diels-Alder reaction between phenyldi[(Z)prop-1-enyl]phosphine and 1-phenyl-3,4-dimethylphosphole.

引用

页码：751 / 752

页数：2

共 16 条

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