Nanostructured sulfur cathodes

被引：1818

作者：

Yang, Yuan ^{[1
]}

Zheng, Guangyuan ^{[2
]}

Cui, Yi ^{[1
,3
]}

机构：

[1] Stanford Univ, Dept Mat Sci & Engn, Stanford, CA 94305 USA

[2] Stanford Univ, Dept Chem Engn, Stanford, CA 94305 USA

[3] Stanford Inst Mat & Energy Sci, SLAC Natl Accelerator Lab, Menlo Pk, CA 94025 USA

来源：

CHEMICAL SOCIETY REVIEWS | 2013年 / 42卷 / 07期

关键词：

GLYCOL) DIMETHYL ETHER; CARBON NANOTUBES COMPOSITE; ELECTROCHEMICAL PROPERTIES; HIGH-CAPACITY; DISCHARGE PROCESS; LITHIUM BATTERIES; GRAPHENE OXIDE; PERFORMANCE; ELECTRODE; CYCLE;

D O I：

10.1039/c2cs35256g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Rechargeable Li/S batteries have attracted significant attention lately due to their high specific energy and low cost. They are promising candidates for applications, including portable electronics, electric vehicles and grid-level energy storage. However, poor cycle life and low power capability are major technical obstacles. Various nanostructured sulfur cathodes have been developed to address these issues, as they provide greater resistance to pulverization, faster reaction kinetics and better trapping of soluble polysulfides. In this review, recent developments on nanostructured sulfur cathodes and mechanisms behind their operation are presented and discussed. Moreover, progress on novel characterization of sulfur cathodes is also summarized, as it has deepened the understanding of sulfur cathodes and will guide further rational design of sulfur electrodes.

引用

页码：3018 / 3032

页数：15

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