Main group and transition metal compounds with silanediolate [R2SiO2]2- and α,ω-siloxane diolate [O(R2SiO)n]2- ligands

被引：87

作者：

King, L ^{[1
]}

Sullivan, AC ^{[1
]}

机构：

[1] Univ London Queen Mary & Westfield Coll, Dept Chem, London E1 4NS, England

来源：

COORDINATION CHEMISTRY REVIEWS | 1999年 / 189卷

关键词：

main-group; transition metals; siloxy fragments; metallasiloxane compounds;

D O I：

10.1016/S0010-8545(99)00115-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

This review is concerned solely with main-group and transition metal compounds incorporating D-n siloxy fragments of the type: O(R2SiO)(n). Various reported routes to these metallasiloxane compounds from a range of ligand sources are discussed. Reactions involving siloxanolate ligand transfer with oligomerisation are featured. General structural and spectroscopic features of the compounds are outlined. A summary of reported chemistry for these metallasiloxane compounds is included. Selected information relating to the synthesis, structure and structural parameters of compounds is provided in tables organised according to periodic groups. (C) 1999 Elsevier Science S.A. All rights reserved.

引用

页码：19 / 57

页数：39

共 63 条

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