Alcohol cross-coupling reactions catalyzed by Ru and Ir terpyridine complexes

被引:69
作者
Gnanamgari, Dinakar [1 ]
Leung, Chin Hin [1 ]
Schley, Nathan D. [1 ]
Hilton, Sheena T. [1 ]
Crabtree, Robert H. [1 ]
机构
[1] Yale Chem Dept, New Haven, CT 06511 USA
关键词
D O I
10.1039/b815547j
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Primary alcohols can be coupled with secondary benzylic alcohols by an air-stable catalytic system involving terpyridine ruthenium or iridium complexes.
引用
收藏
页码:4442 / 4445
页数:4
相关论文
共 39 条
[1]   Evidence for a NiI active species in the catalytic cross-coupling of alkyl electrophiles [J].
Anderson, TJ ;
Jones, GD ;
Vicic, DA .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (26) :8100-8101
[2]   SYNTHESIS AND STRUCTURE OF [(ETA-C5ME5)IR(CO)]2 [J].
BALL, RG ;
GRAHAM, WAG ;
HEINEKEY, DM ;
HOYANO, JK ;
MCMASTER, AD ;
MATTSON, BM ;
MICHEL, ST .
INORGANIC CHEMISTRY, 1990, 29 (10) :2023-2025
[3]   From ruthenium(II) to iridium(III): 15 years of triads based on bis-terpyridine complexes [J].
Baranoff, E ;
Collin, JP ;
Flamigni, L ;
Sauvage, JP .
CHEMICAL SOCIETY REVIEWS, 2004, 33 (03) :147-155
[4]   TUNING THE REACTIVITIES OF RUTHENIUM-OXO COMPLEXES WITH ROBUST LIGANDS - A RUTHENIUM(IV)-OXO COMPLEX OF 6,6'-DICHLORO-2,2'-BIPYRIDINE AS AN ACTIVE OXIDANT FOR STOICHIOMETRIC AND CATALYTIC ORGANIC OXIDATION [J].
CHE, CM ;
HO, C ;
LAU, TC .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1991, (08) :1901-1907
[5]   Enantioselective palladium catalyzed allylic substitution with chiral pyridine ligands [J].
Chelucci, G ;
Caria, V ;
Saba, A .
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 1998, 130 (1-2) :51-55
[6]   Chiral ligands with pyridine donors in transition metal catalyzed enantioselective cyclopropanation and hydrosilylation reactions [J].
Chelucci, G ;
Gladiali, S ;
Sanna, MG ;
Brunner, H .
TETRAHEDRON-ASYMMETRY, 2000, 11 (16) :3419-3426
[7]   New chiral 2,2′:6′,2"-terpyridines as ligands for asymmetric catalysis:: cyclopropanation and hydrosilylation reactions [J].
Chelucci, G ;
Saba, A ;
Vignola, D ;
Solinas, C .
TETRAHEDRON, 2001, 57 (06) :1099-1104
[8]   Ruthenium-catalyzed one-pot β-alkylation of secondary alcohols with primary alcohols [J].
Cho, CS ;
Kim, BT ;
Kim, HS ;
Kim, TJ ;
Shim, SC .
ORGANOMETALLICS, 2003, 22 (17) :3608-3610
[9]   Synthesis and photophysical properties of iridium(III) bisterpyridine and its homologues: a family of complexes with a long-lived excited state [J].
Collin, JP ;
Dixon, IM ;
Sauvage, JP ;
Williams, JAG ;
Barigelletti, F ;
Flamigni, L .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (21) :5009-5016
[10]   NHC ligands versus cyclopentadienyls and phosphines as spectator ligands in organometallic catalysis [J].
Crabtree, RH .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2005, 690 (24-25) :5451-5457