Toward the creation of NMR Databases in chiral solvents: Bidentate chiral NMR solvents for assignment of the absolute configuration of acyclic secondary alcohols

被引:61
作者
Kobayashi, Y [1 ]
Hayashi, N [1 ]
Kishi, Y [1 ]
机构
[1] Harvard Univ, Dept Chem & Biol Chem, Cambridge, MA 02138 USA
关键词
D O I
10.1021/ol0171160
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The absolute configuration of acyclic secondary alcohols can be established from analysis of the chemical shift behaviors of the adjacent carbons in bidentate chiral solvents (R,R)- and (S,S)-1d as formulated in the boxed illustration.
引用
收藏
页码:411 / 414
页数:4
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