Chalcogenide-bridged cuboidal clusters with M4Q4 (M = Mo, W; Q = S, Se, Te) cores

被引：85

作者：

Hernández-Molina, R

Sykes, AG ^{[1
]}

机构：

[1] Univ Newcastle, Dept Chem, Newcastle Upon Tyne NE1 7RU, Tyne & Wear, England

[2] Univ La Laguna, Dept Inorgan Chem, Tenerife 38200, Spain

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1999年 / 18期

关键词：

D O I：

10.1039/a904740i

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Cuboidal cluster complexes having M(4)Q(4) cores made up of transition and main group metals (M), and non-metallic e.g. chalcogenide elements (Q), constitute a rapidly expanding area of inorganic chemistry. Extensive preparation, structural and reactivity studies have been carried out on the Group 6 metals (M = Mo, W) and chalcogenide (Q = S, Se, Te) clusters, and are the main focus of this perspective. The aqueous solution chemistry provides an important reference point in considering redox and other relevant properties.

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页码：3137 / 3148

页数：12

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