1H NMR spectroscopic characterization of solutions of Sepia melanin, Sepia melanin free acid and human hair melanin

被引:60
作者
Katritzky, AR [1 ]
Akhmedov, NG [1 ]
Denisenko, SN [1 ]
Denisko, OV [1 ]
机构
[1] Univ Florida, Dept Chem, Ctr Heterocycl Cpds, Gainesville, FL 32611 USA
来源
PIGMENT CELL RESEARCH | 2002年 / 15卷 / 02期
关键词
Sepia melanin; Sepia melanin free acid; solution nuclear magnetic resonance;
D O I
10.1034/j.1600-0749.2002.1o062.x
中图分类号
Q2 [细胞生物学];
学科分类号
071009 ; 090102 ;
摘要
A H-1 nuclear magnetic resonance study of Sepia melanin, Sepia melanin free acid (Sepia MFA) and human hair melanin was carried out in deuterium oxide solution at pH 10-11. The empirical formula of Sepia MFA was calculated and used to estimate the number of protons in the aromatic region of the Sepia MFA polymeric chain and to suggest a possible monomeric unit profile.
引用
收藏
页码:93 / 97
页数:5
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