Spin crossover in iron(II) complexes of 3,5-di(2-pyridyl)-1,2,4-triazoles and 3,5-di(2-pyridyl)-1,2,4-triazolates

被引:188
作者
Kitchen, Jonathan A. [1 ]
Brooker, Sally [1 ]
机构
[1] Univ Otago, MacDiarmid Inst Adv Mat & Nanotechnol, Dunedin, New Zealand
关键词
spin crossovers; iron; triazole; structure; synthesis; magnetism;
D O I
10.1016/j.ccr.2007.11.010
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The iron coordination chemistry of 3,5-di(2-pyridyl)-1,2,4-triazoles and 3,5-di(2-pyridyl)-1,2,4-triazolates is reviewed. This includes both mononuclear and dinuclear complexes, and both iron(II) and iron(III) oxidation states. The main focus is on the synthesis, structure and magnetic properties of these complexes. (C) 2007 Elsevier B.V. All rights reserved.
引用
收藏
页码:2072 / 2092
页数:21
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