Spin crossover in iron(II) complexes of 3,5-di(2-pyridyl)-1,2,4-triazoles and 3,5-di(2-pyridyl)-1,2,4-triazolates

被引：188

作者：

Kitchen, Jonathan A. ^{[1
]}

Brooker, Sally ^{[1
]}

机构：

[1] Univ Otago, MacDiarmid Inst Adv Mat & Nanotechnol, Dunedin, New Zealand

来源：

COORDINATION CHEMISTRY REVIEWS | 2008年 / 252卷 / 18-20期

关键词：

spin crossovers; iron; triazole; structure; synthesis; magnetism;

D O I：

10.1016/j.ccr.2007.11.010

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The iron coordination chemistry of 3,5-di(2-pyridyl)-1,2,4-triazoles and 3,5-di(2-pyridyl)-1,2,4-triazolates is reviewed. This includes both mononuclear and dinuclear complexes, and both iron(II) and iron(III) oxidation states. The main focus is on the synthesis, structure and magnetic properties of these complexes. (C) 2007 Elsevier B.V. All rights reserved.

引用

页码：2072 / 2092

页数：21

共 76 条

[71] trans-Bis[4-(4-methylphenyl)-3,5-di-2-pyridyl-4H-1,2,4-triazolel]diperchlorato-κ2O-copper(II) [J].

Zhang, SP ;

Liu, ZD ;

Ma, JL ;

Yang, S ;

Shao, SC .

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2005, 61 :M423-M424

[72] Polymetallic, self assembled grids and clusters - Structural and magnetic properties [J].

Zhao, L ;

Matthews, CJ ;

Xu, ZQ ;

Thompson, LK ;

Miller, DO .

MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 2002, 376 (01) :389-397

[73] Syntheses, crystal structures and properties of the novel Co(II) and Ni(II) complexes with 4-(p-methylphenyl)-3,5-bis(pyridin-2-yl)-1,2,4-triazole [J].

Zhu, DR ;

Song, Y ;

Xu, Y ;

Zhang, Y ;

Raj, SSS ;

Fun, HK ;

You, XZ .

POLYHEDRON, 2000, 19 (18-19) :2019-2025

[74] Syntheses, crystal structures and spectroscopic properties of the novel complexes [M(MOBPT)2* (H2O)2](ClO4)2• 4H2O (M = CoII and NiII) [J].

Zhu, DR ;

Song, Y ;

Liu, YK ;

Xu, Y ;

Zhang, Y ;

You, XZ ;

Raj, SSS ;

Fun, HK .

TRANSITION METAL CHEMISTRY, 2000, 25 (05) :589-593

[75] A novel bis(trans-thiocyanate)iron (II) spin-transition molecular material with bidentate triaryltriazole ligands and its bis(cis-thiocyanate)iron (II) high-spin isomer [J].

Zhu, DR ;

Xu, Y ;

Yu, Z ;

Guo, ZJ ;

Sang, H ;

Liu, T ;

You, XZ .

CHEMISTRY OF MATERIALS, 2002, 14 (02) :838-843

[76] Crystal and molecular structure of a novel complex [Mn(MOBPT)(H2O)2(NCS)2] (MOBPT=4-(p-methoxyphenyl)-3,5-bis (pyridin-2-yl)-1,2,4-triazole) [J].

Zhu, DR ;

Xu, Y ;

Mei, YH ;

Shi, YJ ;

Tu, C ;

You, XZ .

JOURNAL OF MOLECULAR STRUCTURE, 2001, 559 (1-3) :119-125

← 1 2 3 4 5 6 7 8 →