Recent developments of surface light scattering as a tool for optical-rheology of polymer monolayers

被引:44
作者
Cicuta, P
Hopkinson, I
机构
[1] Univ Cambridge, Cavendish Lab, Cambridge CB3 0HE, England
[2] Univ Manchester, Dept Phys, Manchester M60 1QD, Lancs, England
关键词
surface quasi-elastic light scattering; SQELS; langmair monolayer; surface rheology; dilational viscoelasticity;
D O I
10.1016/j.colsurfa.2003.11.025
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Surface quasi-elastic light scattering (SQELS) is an application of dynamic light scattering to measure the dynamics of the thermal roughness of liquid surfaces. An analysis of the spectrum of thermal fluctuations provides information on surface properties like tension and elasticity. In this work we will focus particularly on its use to study polymer or polymer-like Langmuir monolayers. We review work in this area and give an up-to-date overview of the method. Important advances have very recently taken place in the theoretical understanding of this problem, and this has allowed improvements in the analysis of the experimental data. A practical method to estimate the region of physical parameters that can be reliably measured is presented. (C) 2003 Elsevier B.V. All rights reserved.
引用
收藏
页码:97 / 107
页数:11
相关论文
共 54 条
[31]  
Lucassen-Reynders E.H., 1969, ADV COLLOID INTERFAC, V2, P347, DOI 10.1016/0001-8686(70)80001-x
[32]   Fast multi-tau real-time software correlator for dynamic light scattering [J].
Magatti, D ;
Ferri, F .
APPLIED OPTICS, 2001, 40 (24) :4011-4021
[33]   SURFACE FLUCTUATION SPECTROSCOPY - COMMENTS ON EXPERIMENTAL-TECHNIQUE AND CAPILLARY RIPPLE THEORY [J].
MANN, JA ;
EDWARDS, RV .
REVIEW OF SCIENTIFIC INSTRUMENTS, 1984, 55 (05) :727-731
[34]   Surface fluctuation spectroscopy by surface-light-scattering spectroscopy [J].
Mann, JA ;
Crouser, PD ;
Meyer, WV .
APPLIED OPTICS, 2001, 40 (24) :4092-4112
[35]   LIGHT SCATTERING FROM SURFACE-WAVES ON CARBON DIOXIDE NEAR CRITICAL POINT [J].
MEUNIER, J .
JOURNAL DE PHYSIQUE, 1969, 30 (11-1) :933-&
[36]   Hybrid reflection-transmission surface light-scattering instrument with reduced sensitivity to surface sloshing [J].
Meyer, WV ;
Lock, JA ;
Cheung, HM ;
Taylor, TW ;
Tin, P ;
Mann, JA .
APPLIED OPTICS, 1997, 36 (30) :7605-7614
[37]   Advances in surface-light-scattering instrumentation and analysis: noninvasive measuring of surface tension, viscosity, and other interfacial parameters [J].
Meyer, WV ;
Wegdam, GH ;
Fenistein, D ;
Mann, JA .
APPLIED OPTICS, 2001, 40 (24) :4113-4133
[38]  
Miles DG, 2002, J CHEM EDUC, V79, P1007
[39]   Dilational and shear rheology of adsorption layers at liquid interfaces [J].
Miller, R ;
Wustneck, R ;
Kragel, J ;
Kretzschmar, G .
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 1996, 111 (1-2) :75-118
[40]   Surface viscoelastic properties of spread films of a polysilylene-poly(ethylene oxide) multiblock copolymer at the air-water interface [J].
Milling, AJ ;
Richards, RW ;
Hiorns, RC ;
Jones, RG .
MACROMOLECULES, 2000, 33 (07) :2651-2661