Performance and Photovoltaic Response of Polymer-Doped Carbon Nanotube p-n Diodes

被引：35

作者：

Abdula, Daner ^{[1
]}

Shim, Moonsub ^{[1
]}

机构：

[1] Univ Illinois, Dept Mat Sci & Engn, Urbana, IL 61801 USA

来源：

ACS NANO | 2008年 / 2卷 / 10期

关键词：

carbon nanotube; diode; p-n; photovoltaic; Raman spectroscopy;

D O I：

10.1021/nn800368s

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two terminal abrupt junction diodes are fabricated from single semiconducting carbon nanotubes with simple photopatterned polymer layers defining air-stable p- and n-regions. These intratube diodes show nearly ideal behavior with relatively low series resistance and no sign of Zener breakdown at room temperature. Spatial doping profiles measured by micro-Raman spectroscopy and selective electrochemical gating of the n-region indicate that diode performance depends strongly on relative doping levels. A short circuit current of 1.4 nA with an open circuit voltage of 205 mV are measured when illuminated to saturation.

引用

页码：2154 / 2159

页数：6

共 36 条

[21] Conductivity enhancement in single-walled carbon nanotube bundles doped with K and Br [J].

Lee, RS ;

Kim, HJ ;

Fischer, JE ;

Thess, A ;

Smalley, RE .

NATURE, 1997, 388 (6639) :255-257

[22]

LI YF, 2007, APPL PHYS LETT, V90, P74701

[23]

Mahan G. D., 1990, Many-Particle Physics, DOI 10.1007/978-1-4613-1469-1

[24] Polymer electrolyte gating of carbon nanotube network transistors [J].

Ozel, T ;

Gaur, A ;

Rogers, JA ;

Shim, M .

NANO LETTERS, 2005, 5 (05) :905-911

[25] Evidence for charge transfer in doped carbon nanotube bundles from Raman scattering [J].

Rao, AM ;

Eklund, PC ;

Bandow, S ;

Thess, A ;

Smalley, RE .

NATURE, 1997, 388 (6639) :257-259

[26] A tunable carbon nanotube electromechanical oscillator [J].

Sazonova, V ;

Yaish, Y ;

Üstünel, H ;

Roundy, D ;

Arias, TA ;

McEuen, PL .

NATURE, 2004, 431 (7006) :284-287

[27] Effects of oxygen on the electron transport properties of carbon nanotubes: Ultraviolet desorption and thermally induced processes [J].

Shim, M ;

Back, JH ;

Ozel, T ;

Kwon, KW .

PHYSICAL REVIEW B, 2005, 71 (20)

[28] Polymer functionalization for air-stable n-type carbon nanotube field-effect transistors [J].

Shim, M ;

Javey, A ;

Kam, NWS ;

Dai, HJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (46) :11512-11513

[29] Insights on charge transfer doping and intrinsic phonon line shape of carbon nanotubes by simple polymer adsorption [J].

Shim, M ;

Ozel, T ;

Gaur, A ;

Wang, CJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (23) :7522-7530

[30] Highly efficient Gating and doping of carbon nanotubes with polymer electrolytes [J].

Siddons, GP ;

Merchin, D ;

Back, JH ;

Jeong, JK ;

Shim, M .

NANO LETTERS, 2004, 4 (05) :927-931

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