Asymmetric Ion-Pairing Catalysis

被引：829

作者：

Brak, Katrien ^{[1
]}

Jacobsen, Eric N. ^{[1
]}

机构：

[1] Harvard Univ, Dept Chem & Chem Biol, Cambridge, MA 02138 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 02期

关键词：

anion-binding catalysis; asymmetric catalysis; chiral anions; ion pairs; phase-transfer catalysis; PHASE-TRANSFER CATALYSTS; CHIRAL BRONSTED ACID; QUATERNARY AMMONIUM BROMIDES; TRANSITION-METAL CATALYSIS; PICTET-SPENGLER REACTIONS; MANNICH-TYPE REACTION; ALPHA-AMINO-ACIDS; ENANTIOSELECTIVE SYNTHESIS; KINETIC RESOLUTION; PHOSPHORIC-ACID;

D O I：

10.1002/anie.201205449

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Charged intermediates and reagents are ubiquitous in organic transformations. The interaction of these ionic species with chiral neutral, anionic, or cationic small molecules has emerged as a powerful strategy for catalytic, enantioselective synthesis. This review describes developments in the burgeoning field of asymmetric ion-pairing catalysis with an emphasis on the insights that have been gleaned into the structural and mechanistic features that contribute to high asymmetric induction.

引用

页码：534 / 561

页数：28

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